期刊
CHEMISTRYSELECT
卷 6, 期 45, 页码 12644-12651出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/slct.202103212
关键词
Cryogel; click chemistry; electrochemistry; ferrocene; porous materials; voltammetry
资金
- Scientific and Technical Research Council of Turkey (TUBITAK) [114Z286]
The functionalization of macroporous polyacrylamide-based cryogel with ferrocene was achieved using click chemistry, preserving the unique properties of the cryogel. Detailed characterization of the functionalized cryogel was performed to confirm the presence of ferrocene and its electroactivity.
Ferrocene (Fc) functionalization of macroporous polyacrylamide-based cryogel (PAAm-Epx) is achieved by click chemistry. For this purpose, firstly, PAAm-Epx cryogel with azide functionality (PAAm-N-3) is prepared by using acryalmide (AAm) as the monomer and allyl glycidyl ether (AGE) as the co-monomer followed by subsequent ring opening reaction of epoxide ring of AGE in acidic medium. Azide groups of PAAm-N-3 is then modified with ethynyl ferrocene, leading to the redox active cryogel (PAAm-Fc) together with preserving the unique characteristic properties of the virgin PAAm-Epx cryogel. Swelling, mechanical and morphological behaviours of PAAm-Epx, PAAm-N-3 and PAAm-Fc are investigated. Detailed characterization of the PAAm-Fc is carried out by several techniques such as FTIR (Fourier Transform Infrared Spectroscopy), Scanning electron microscopy with energy dispersive X-ray spectroscopy (SEM-EDX), Inductively Coupled Plasma Optical Emmision Spectrometry (ICP-OES, Cyclic (CV), and Differential Pulse Voltammetry (DPV). Electrochemical analysis confirms the electroactivity and the presence of chemically linked ferrocene unit to the cryogel.
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