Co-detection of carmoisine and tartrazine by carbon paste electrode modified with ionic liquid and MoO3/WO3 nanocomposite

A carbon paste electrode modified with ionic liquid (1-butyl-3-methylimidazolium hexafluorophosphate) and MoO3/WO3 nanocomposite (MoO3/WO3/ILCPE) as an electrochemical sensor was developed for co-detection of tartrazine and carmoisine. Differential pulse voltammetry (DPV) method was applied to evaluate the electrochemical responses of tartrazine and carmoisine, the results of which confirmed a significant improvement of electrochemical behaviors on the modified electrode surface. High peak separation of oxidation (800 mV) made possible the co-detection of tartrazine and carmoisine. The DPV data in 0.1 M phosphate buffer solution at a pH value of 7.0 made it possible to develop a method for determining carmoisine in the dynamic range of 0.5-100 mu M with the limit of detection of 0.15 mu M. Also, the fabricated sensor showed good stability and selectivity. Our modified sensor could successfully detect these compounds in the real fruit specimens.

Automated summary

A carbon paste electrode modified with ionic liquid and MoO3/WO3 nanocomposite was developed for co-detection of tartrazine and carmoisine using differential pulse voltammetry. The method exhibited improved electrochemical behaviors and high peak separation for the two compounds. The sensor showed good stability, selectivity, and successful detection of the compounds in real fruit specimens.