期刊
ENERGY SCIENCE & ENGINEERING
卷 10, 期 5, 页码 1601-1613出版社
WILEY
DOI: 10.1002/ese3.1064
关键词
biomass-derived reductants; catalytic mechanism; CO2 reduction; formic acid; hydrothermal conversion; metalic catalysts
资金
- State Key Program of Natural Science Foundation of China [21436007]
- National Natural Science Foundation of China [21978170]
- Natural Science Foundation of Shanghai [19ZR1424800]
- Oceanic Interdisciplinary Program of Shanghai Jiao Tong University [SL2020MS022]
- Centre of Hydrogen Science, Shanghai Jiao Tong University, China
- Start-up Fund for Youngman Research at SJTU
Converting CO2 into value-added chemicals is environmentally and economically beneficial, and hydrothermal reduction is a promising strategy. This paper summarizes the recent advances in converting CO2 into formic acid using metal- and biomass-based catalysts under hydrothermal conditions, and discusses the effects of several experimental variables on the formic acid yield.
Converting CO2, a major component of greenhouse gas in the atmosphere, into value-added fine chemicals is beneficial from environmental and economic aspects. Except for various methods for CO2 reduction such as thermal catalysis, photocatalysis, electrocatalysis and biological reduction, hydrothermal reduction of CO2 to organics is becoming a novel and promising strategy. The hydrogen formed in situ from high-temperature water could avoid the serious issues of hydrogen storage and transportation. This paper summarizes the recent advances on CO2 conversion to formic acid with metal- and biomass-based compounds under hydrothermal conditions mainly focusing on the role of high-temperature water, autocatalysis mechanism of metal reductants, and interfacial catalysis mechanism of metal/metal oxides. The effects of several experimental variables including temperature, reaction time and pH of the solution on formic acid yield are systematically illustrated as well. Finally, future efforts for fundamental researches and industrial applications of hydrothermal CO2 reduction are discussed.
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