期刊
JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T
卷 15, 期 -, 页码 4573-4579出版社
ELSEVIER
DOI: 10.1016/j.jmrt.2021.10.080
关键词
Metal matrix composites; Liquid metal dealloying; Mechanical properties; Heterostructure composites; Hierarchical structure
资金
- JSPS KAKENHI [JP20J14001]
- GP-MS at Tohoku University
- National Research Foundation of Korea - Korea government (MSIT) [NRF-2021R1C1C1007645]
- Ministry of Education, Culture, Sports, Science, and Technology (MEXT, Japan) [18H05452]
Liquid metal dealloying (LMD) has attracted attention for its ability to produce 3D interconnected non-noble metallic materials, and the addition of Ni alloying element to soft Mg phase has resulted in a hierarchical heterostructured composite with high yield strength and noticeable elongation. The complex 3D morphology of ligament and lamellar geometries in the composite prevent the early fracture of brittle Mg-Mg2Ni lamellar phase, offering insights for hierarchical HS materials with outstanding mechanical properties for structural applications.
Liquid metal dealloying (LMD) has recently attracted significant attention. Because the LMD process enables the production of three-dimensional (3D) interconnected non-noble metallic materials. In addition, the metallic melt medium is useful for the development of heterostructure (HS) metal-metal composites. However, the solidified liquid metal phase (low melting point metals such as Mg, Bi, Sn, or Cu) has a much lower strength than the developed ligament phase (e.g., Fe, FeCr, Ti, etc.). In this study, the soft Mg phase was strengthened by adding alloying element of Ni. A eutectic composition of Mg-10 at.% Ni melt leads to the formation of fine eutectic structure of (Mg-Mg2Ni) within 3D interconnected morphology. This hierarchical heterostructured composite consisted of FeCr ligament and Mg-Mg2Ni lamellar, and a high yield strength of 280 MPa and a noticeable elongation (1.5%) were achieved. The complex 3D morphology of ligament and lamellar geometrically constraint each other, and it prevents the early fracture of brittle Mg-Mg2Ni lamellar phase. The alloy design for the LMD melt gives insights for hierarchical HS materials with outstanding mechanical properties for structural applications. (C) 2021 The Authors. Published by Elsevier B.V.
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