期刊
JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T
卷 15, 期 -, 页码 3850-3866出版社
ELSEVIER
DOI: 10.1016/j.jmrt.2021.10.018
关键词
One-part geopolymer; High calcium fly ash; Sodium aluminate; Anhydrous sodium metasilicate
资金
- Ministry of Higher Education Malaysia [FRGS/1/2020/TK01/UNIMAP/02/2]
This study investigates the effects of different solid alkali activators on one-part geopolymers, finding that the choice of activator significantly affects the properties and microstructural changes of the OPGs. Despite the differences, all the OPGs studied are suitable for building material applications.
This paper investigates the effect of varying solid alkali activators on the fresh and hardened properties and microstructural changes of one-part geopolymers (OPGs). Single and binary solid alkali activators were used to activate high calcium fly ash. The alkali activators were either solely sodium metasilicate (Na2SiO3) or a combination of sodium aluminate (NaAlO2) and sodium metasilicate (Na2SiO3)(.) The OPG activated with anhydrous Na2SiO3 achieved an excellent 28-day compressive strength of 83.6 MPa while OPG activated with NaAlO2 and Na2SiO3 attained a compressive strength of 45.1 MPa. The Na(2)SiO(3)activated OPG demonstrated better fluidity than the OPG activated with NaAlO2 and Na2SiO3 due to the thixotropic behaviour caused by the NaAlO2. The Na2SiO3-activated OPG consisted of sodium-calcium aluminium silicate hydrate ((N,C)-A-S-H) gel phase, while the OPG activated with NaAlO2 and Na2SiO3 comprised of the coexistence of sodium aluminium silicate hydrate (N-A-S-H) and calcium aluminium silicate hydrate (C-A-S-H) gel phases. Regardless of the distinctive properties, the OPGs are adequate for building materials applications. (C) 2021 The Author(s). Published by Elsevier B.V.
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