期刊
JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T
卷 16, 期 -, 页码 570-580出版社
ELSEVIER
DOI: 10.1016/j.jmrt.2021.12.040
关键词
Lignin; Porous carbon; Texture properties; Supercapacitors; Specific capacitance
资金
- National Promotion Project of China [2020133136]
- National Key Research and Development Plan of China [2016YFE0201800]
The specific surface area and pore-wall thickness together determine the specific capacitance of porous carbon materials, while volumetric surface area can be used as a general predictor of specific capacitance at low current densities.
Searching for good-natured feedstocks and understanding the texture property of porous carbon/specific capacitance relationships have long been highly desirable. Herein, hydrothermal and KOH were used to assist the synthesis of lignin-derived porous carbons (LPCs) with high specific surface area for supercapacitors. The as-synthesized LPC-150 and LPC200 had a specific surface area of 3033.88 m2/g and 3178.36 m2/g, respectively, with a specific capacitance of 214.03 F/g and 201.69 F/g at 0.50 A/g. In the range from 2448 m2/g to 3178 m2/g, increasing the specific surface area again possesses no remarkable effect on the specific capacitance. Meanwhile, the specific surface area and the pore-wall thickness together determine the specific capacitance. When using a three-electrode configuration with a 6 mol/L KOH electrolyte, the volumetric surface area rather than the ultrahigh specific surface area can be employed as a general predictor of specific capacitance in the low current density ranging from 0.50 to 10.00 A/g. (c) 2021 The Author(s). Published by Elsevier B.V. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).
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