4.7 Article

Helical copper-porphyrinic framework nanoarrays for highly efficient CO2 electroreduction

相关参考文献

注意:仅列出部分参考文献,下载原文获取全部文献信息。
Article Engineering, Environmental

Construction of atomically dispersed Cu-N4 sites via engineered coordination environment for high-efficient CO2 electroreduction

Huiyuan Cheng et al.

Summary: Highly exposed atomically dispersed Cu-N-x sites were successfully synthesized through one-step thermal activation, with Cu-N-4 sites exhibiting boosted activity and selectivity by interacting with *COOH intermediate and facilitating desorption of *CO, leading to high CO Faradaic efficiency.

CHEMICAL ENGINEERING JOURNAL (2021)

Article Chemistry, Multidisciplinary

Dynamic Activation of Adsorbed Intermediates via Axial Traction for the Promoted Electrochemical CO2 Reduction

Xinyue Wang et al.

Summary: An axial traction strategy was developed to optimize the electronic structure of the M-N-4 moiety, leading to atomically dispersed nickel sites coordinated with four nitrogen atoms and one axial oxygen atom embedded within the carbon matrix (Ni-N-4-O/C). This Ni-N-4-O/C electrocatalyst exhibited excellent CO2RR performance with a high CO Faradic efficiency close to 100% at -0.9 V, maintaining the CO FE above 90% in a wide potential window. The superior CO2RR activity is attributed to the axial traction effect induced by the Ni-N-4-O active moiety.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Article Chemistry, Physical

In-situ formation of ligand-stabilized bismuth nanosheets for efficient CO2 conversion

Nanhui Li et al.

Summary: This study demonstrates the facile generation of ligand-stabilized under-coordinated surface sites from in situ transformations of metal-organic precursors for highly efficient CO2 conversion. The ligand-stabilized Bi nanosheets exhibit remarkable electrocatalytic performance for CO2 reduction, achieving a high Faradic efficiency of 98% for formate and improved durability over 40 hours.

APPLIED CATALYSIS B-ENVIRONMENTAL (2021)

Article Chemistry, Multidisciplinary

Proton Capture Strategy for Enhancing Electrochemical CO2 Reduction on Atomically Dispersed Metal-Nitrogen Active Sites**

Xinyue Wang et al.

Summary: Electrocatalysts play a crucial role in accelerating the slow electrochemical CO2 reduction process, and a proton capture strategy has been developed to enhance proton transfer and boost the overall ECR process. This strategy, demonstrated using transition-metal nanoparticles and single nickel active sites, is universal for designing high-performance catalysts for various electrochemical reactions.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Review Chemistry, Physical

Recent progress and perspective of electrochemical CO2 reduction towards C2-C5 products over non-precious metal heterogeneous electrocatalysts

Jiayi Chen et al.

Summary: This article summarizes the latest research advances on NPMH electrocatalysts for CO2ER, including nanostructured Cu, Cu-based bimetallic catalysts, Cu-based complexes, and carbon-based Cu-free catalysts for the conversion of CO2 into high-value multicarbon products. The performance of CO2ER for different types of multicarbon products, especially ethanol, ethylene, ethane, acetic acid, propanol, and other C2+ products, is discussed with a focus on the structure-activity relationship.

NANO RESEARCH (2021)

Review Chemistry, Physical

Carbon-Based Materials for Electrochemical Reduction of CO2 to C2+ Oxygenates: Recent Progress and Remaining Challenges

Kun Zhao et al.

Summary: This review summarizes recent progress in the formation of C2+ oxygenates from CO2 reduction on carbon-based materials, highlighting strategies for achieving C-C coupling, the relationship between intermediate adsorption energy and selectivity of oxygenate production, and mechanisms of C2+ oxygenate generation and active site fabrication on carbon-based materials. Challenges and opportunities for electrochemical conversion of CO2 into C2+ oxygenates were discussed.

ACS CATALYSIS (2021)

Article Materials Science, Multidisciplinary

Atomic-level-designed copper atoms on hierarchically porous gold architectures for high-efficiency electrochemical CO2 reduction

Yang Zhao et al.

Summary: The study presents a highly efficient CO2 reduction electrocatalyst with excellent CO Faraday efficiency and stability, showing great potential for practical applications.

SCIENCE CHINA-MATERIALS (2021)

Article Chemistry, Physical

Atomic nickel cluster decorated defect-rich copper for enhanced C2 product selectivity in electrocatalytic CO2 reduction

Xiaolong Zhang et al.

Summary: This work introduces a coordination enabled galvanic replacement method to decorate atomic Ni clusters on defect-rich Cu surface, resulting in significant enhancement of C2 products production in electrocatalytic CO2 reduction. With a surface Ni/Cu ratio of 0.82 %, a 7-fold increase in selectivity for C2 products was observed compared to pristine Cu, attributed to the chemisorption of CO2 on Ni decorated surfaces changing the rate determining step for *CO formation. The catalytic mechanism demonstrated in the Cu-Ni system points to new directions for the development of advanced bimetallic electrocatalysts for producing multi-carbon materials from CO2 reduction.

APPLIED CATALYSIS B-ENVIRONMENTAL (2021)

Review Chemistry, Multidisciplinary

Regulating the oxidation state of nanomaterials for electrocatalytic CO2 reduction

Zhi-Zheng Wu et al.

Summary: Electrochemical carbon dioxide reduction reaction (CO2RR) converts CO2 into value-added chemicals and fuels, addressing renewable energy shortage and environmental pollution. Regulating the oxidation state of catalysts has been identified as an effective method for designing high-performing CO2RR catalysts that can influence catalyst activity and selectivity.

ENERGY & ENVIRONMENTAL SCIENCE (2021)

Review Chemistry, Multidisciplinary

Electrocatalysis for CO2 conversion: from fundamentals to value-added products

Genxiang Wang et al.

Summary: This article provides a comprehensive review of recent research progress on the selective electrocatalytic conversion of CO2 into value-added products. It covers the history and fundamental science of electrocatalytic CO2RR, the design, preparation, and performance evaluation of electrocatalysts, factors influencing the CO2RR, and associated theoretical calculations. Emphasis is placed on emerging trends in selective electrocatalytic conversion of CO2 and discussions on structure-performance relationships and mechanisms.

CHEMICAL SOCIETY REVIEWS (2021)

Review Materials Science, Multidisciplinary

Reticular chemistry in electrochemical carbon dioxide reduction

Yanfang Wang et al.

SCIENCE CHINA-MATERIALS (2020)

Article Chemistry, Multidisciplinary

Ethylene Selectivity in Electrocatalytic CO2 Reduction on Cu Nanomaterials: A Crystal Phase-Dependent Study

Ye Chen et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

Review Chemistry, Multidisciplinary

Organic-Inorganic Hybrid Nanomaterials for Electrocatalytic CO2 Reduction

Chenhuai Yang et al.

Article Chemistry, Multidisciplinary

Intermediate Binding Control Using Metal-Organic Frameworks Enhances Electrochemical CO2 Reduction

Dae-Hyun Nam et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

Review Chemistry, Physical

Engineering pristine 2D metal-organic framework nanosheets for electrocatalysis

Dongdong Zhu et al.

JOURNAL OF MATERIALS CHEMISTRY A (2020)

Article Chemistry, Physical

A cold plasma-activated in situ AgCo surface alloy for enhancing the electroreduction of CO2 to ethanol

Qiang Zhang et al.

JOURNAL OF MATERIALS CHEMISTRY A (2020)

Article Chemistry, Multidisciplinary

Electrochemical Fragmentation of Cu2O Nanoparticles Enhancing Selective C-C Coupling from CO2 Reduction Reaction

Hyejin Jung et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

Article Chemistry, Multidisciplinary

Bismuth Single Atoms Resulting from Transformation of Metal-Organic Frameworks and Their Use as Electrocatalysts for CO2 Reduction

Erhuan Zhang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

Article Multidisciplinary Sciences

Efficient upgrading of CO to C3 fuel using asymmetric C-C coupling active sites

Xue Wang et al.

NATURE COMMUNICATIONS (2019)

Review Chemistry, Multidisciplinary

Metal-organic frameworks for catalysis: State of the art, challenges, and opportunities

Dandan Li et al.

ENERGYCHEM (2019)

Article Chemistry, Multidisciplinary

Helical cobalt borophosphates to master durable overall water-splitting

Prashanth W. Menezes et al.

ENERGY & ENVIRONMENTAL SCIENCE (2019)

Article Chemistry, Multidisciplinary

Mixed Copper States in Anodized Cu Electrocatalyst for Stable and Selective Ethylene Production from CO2 Reduction

Si Young Lee et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

Review Chemistry, Multidisciplinary

Cu-based nanocatalysts for electrochemical reduction of CO2

Huan Xie et al.

NANO TODAY (2018)

Review Materials Science, Multidisciplinary

Recent progress on advanced design for photoelectrochemical reduction of CO2 to fuels

Ning Zhang et al.

SCIENCE CHINA-MATERIALS (2018)

Article Chemistry, Physical

Recent Advances in CO2 Reduction Electrocatalysis on Copper

David Raciti et al.

ACS ENERGY LETTERS (2018)

Review Chemistry, Inorganic & Nuclear

Metal-organic frameworks for direct electrochemical applications

Yuxia Xu et al.

COORDINATION CHEMISTRY REVIEWS (2018)

Review Chemistry, Inorganic & Nuclear

Metal-organic frameworks for electrocatalysis

Pei-Qin Liao et al.

COORDINATION CHEMISTRY REVIEWS (2018)

Article Chemistry, Multidisciplinary

Metal-Organic Frameworks Mediate Cu Coordination for Selective CO2 Electroreduction

Dae-Hyun Nam et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

Review Chemistry, Physical

Understanding heterogeneous electrocatalytic carbon dioxide reduction through operando techniques

Albertus D. Handoko et al.

NATURE CATALYSIS (2018)

Article Chemistry, Physical

High-rate electroreduction of carbon monoxide to multi-carbon products

Matthew Jouny et al.

NATURE CATALYSIS (2018)

Review Chemistry, Multidisciplinary

Electrocatalytic Alloys for CO2 Reduction

Jingfu He et al.

CHEMSUSCHEM (2018)

Review Chemistry, Multidisciplinary

Controllable design of tunable nanostructures inside metal-organic frameworks

Liyu Chen et al.

CHEMICAL SOCIETY REVIEWS (2017)

Review Chemistry, Multidisciplinary

Metal-Organic Frameworks as Platforms for Functional Materials

Yuanjing Cui et al.

ACCOUNTS OF CHEMICAL RESEARCH (2016)

Article Multidisciplinary Sciences

A metal-free electrocatalyst for carbon dioxide reduction to multi-carbon hydrocarbons and oxygenates

Jingjie Wu et al.

NATURE COMMUNICATIONS (2016)

Review Chemistry, Multidisciplinary

Growth Actuated Bending and Twisting of Single Crystals

Alexander G. Shtukenberg et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2014)

Editorial Material Chemistry, Multidisciplinary

Metal-Organic Frameworks (MOFs)

Hong-Cai ''Joe'' Zhou et al.

CHEMICAL SOCIETY REVIEWS (2014)

Review Chemistry, Multidisciplinary

Screw Dislocation Driven Growth of Nanomaterials

Fei Meng et al.

ACCOUNTS OF CHEMICAL RESEARCH (2013)

Editorial Material Chemistry, Multidisciplinary

Introduction to Metal-Organic Frameworks

Hong-Cai Zhou et al.

CHEMICAL REVIEWS (2012)

Article Chemistry, Multidisciplinary

Rational Solution Growth of α-FeOOH Nanowires Driven by Screw Dislocations and Their Conversion to α-Fe2O3 Nanowires

Fei Meng et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2011)