4.6 Article

Ionic and Electronic Conductivities of Lithium Argyrodite Li6PS5Cl Electrolytes Prepared via Wet Milling and Post-Annealing

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FRONTIERS IN CHEMISTRY
卷 9, 期 -, 页码 -

出版社

FRONTIERS MEDIA SA
DOI: 10.3389/fchem.2021.778057

关键词

all-solid-state battery; lithium argyrodite; milling; conductivity; discharge capacity

资金

  1. National Research Foundation of Korea (NRF) [NRF-2020M3D1A2102918]
  2. Technology Development Program to Solve Climate Changes of the National Research Foundation (NRF) - Ministry of Science, ICT & Future Planning [2017M1A2A2044927]
  3. National Research Foundation of Korea [2020M3D1A2102918, 2017M1A2A2044927] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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Wet-mechanical milling and post-annealing at 500 degrees C for 4 h were used to synthesize Li6PS5Cl electrolyte powder with excellent electrochemical properties. The choice of solvent does not significantly affect ionic conductivity but does have an impact on electronic conductivity. The use of xylene and toluene can produce Li6PS5Cl electrolyte powder with low electronic and comparable ionic conductivities.
Lithium argyrodite Li6PS5Cl powders are synthesized from Li2S, P2S5, and LiCl via wet milling and post-annealing at 500 degrees C for 4 h. Organic solvents such as hexane, heptane, toluene, and xylene are used during the wet milling process. The phase evolution, powder morphology, and electrochemical properties of the wet-milled Li6PS5Cl powders and electrolytes are studied. Compared to dry milling, the processing time is significantly reduced via wet milling. The nature of the solvent does not affect the ionic conductivity significantly; however, the electronic conductivity changes noticeably. The study indicates that xylene and toluene can be used for the wet milling to synthesize Li6PS5Cl electrolyte powder with low electronic and comparable ionic conductivities. The all-solid-state cell with the xylene-processed Li6PS5Cl electrolyte exhibits the highest discharge capacity of 192.4 mAh center dot g(-1) and a Coulombic efficiency of 81.3% for the first discharge cycle.

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