期刊
ORGANIC CHEMISTRY FRONTIERS
卷 9, 期 3, 页码 649-659出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1qo01688a
关键词
-
资金
- NSERC
Experimental and computational studies have shown that the new catalysts cis- and trans-4,5-ethano-proline are as active as proline or other common catalysts, with the trans-ethano-proline exhibiting high enantioselectivity. A thorough theoretical analysis of the electronic factors influencing catalysis has been reported.
The catalysis of the Hajos-Parrish reaction by cis- and trans-4,5-ethano-proline was explored experimentally and computationally with DFT (omega B97X-D and MN15) and DLPNO-CCSD(T). Both of the new catalysts are as active as proline or cis- and trans-4,5-methano-proline, with the trans-ethano-proline being as enantioselective as proline. A thorough theoretical analysis of the electronic factors influencing catalysis is reported.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据