期刊
ORGANIC CHEMISTRY FRONTIERS
卷 9, 期 3, 页码 853-873出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1qo01512e
关键词
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资金
- Natural Science Foundation of the Jiangsu Higher Education Institutions of China [19KJB150020]
- construction project of the Key Laboratory of State Ethnic Affairs Commission (DDA office) [91]
In summary, the activation and functionalization of C-F bonds are important tools for organic synthesis. Recent developments using photochemical or electrochemical methods have shown significant progress in this field, providing alternative approaches to traditional chemical methods.
The activation and functionalization of C-F bonds under mild conditions can serve as an important tool for organic syntheses including the modification of pharmaceuticals and agrochemicals and the synthesis of value-added chemicals. However, owing to their high energy and low activity, C-F bonds are difficult to activate. Thus, the direct activation of the C-F bond under mild or transition-metal-free conditions is a challenging research topic. Recently, photochemical or electrochemical C-F bond activation and functionalization has been evaluated as a scalable and sustainable approach that applies photons or electricity, respectively, to replace dangerous chemical oxidants or metal catalysts. To date, the achievements in this field have attracted great attention; however, reviews on photochemical or electrochemical C-F bond activation and functionalization are scarce. In this review, we summarize the recent significant developments in this rapidly growing area, mainly focusing on the reaction design and mechanisms.
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