期刊
FRONTIERS OF CHEMICAL SCIENCE AND ENGINEERING
卷 15, 期 6, 页码 1380-1407出版社
SPRINGER
DOI: 10.1007/s11705-021-2097-z
关键词
hollow carbon spheres; functionalization; noble metal-free; catalysis
资金
- Natural Science Foundation of Shandong province [ZR2019QEM005]
- SDUST Research Fund [2015YQJH101]
- Project of Shandong province Higher Educational Young Innovative Talent Introduction and Cultivation Team [environmental functional material innovation team]
Hollow carbon spheres have attracted great interest due to their high surface area, large surface-to-volume ratio, and reduced transmission lengths. Research has shown that these materials can be combined with noble metal-free hybrids for various applications in catalysis.
Hollow carbon spheres have garnered great interest owing to their high surface area, large surface-tovolume ratio and reduced transmission lengths. Herein, we overview hollow carbon sphere-based materials and their noble metal-free hybrids in catalysis. Firstly, we summarize the key fabrication techniques for various kinds of hollow carbon spheres, with a particular emphasis on controlling pore structure and surface morphology, and then heterogeneous doping as well as their metal-free/ containing hybrids are presented; next, possible applications for non-noble metal/hollow carbon sphere hybrids in the area of energy-related catalysis, including oxygen reduction reaction, hydrogen evolution reaction, oxygen evolution reaction, water splitting, rechargeable Zn-air batteries and pollutant degradation are discussed; finally, we introduce the various challenges and opportunities offered by hollow carbon spheres from the perspective of synthesis and catalysis.
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