期刊
APPLIED SCIENCES-BASEL
卷 11, 期 21, 页码 -出版社
MDPI
DOI: 10.3390/app112110243
关键词
inverse gas chromatography; IGC; metal-organic frameworks; dispersive surface properties; specific surface properties; physicochemical characterization
类别
资金
- National Plan for Science, Technology, and Innovation (MAARIFAH), King Abdul Aziz City for Science and Technology, Kingdom of Saudi Arabia [14-ADV2447-02]
Inverse gas chromatography (IGC) is a useful method for characterizing material surface properties, particularly in the physicochemical characterization of metal-organic frameworks (MOFs), which have unique structure design and properties. The review focuses on the fundamental theory and instrumentation of IGC, highlighting its significant applications in MOF characterization.
The desire to customize the properties of a material through complete control over both its chemical and architectural structure has created a constant and persistent need for efficient and convenient characterization techniques. Inverse gas chromatography (IGC) is considered a useful characterization method for probing the material's surface properties, like its enthalpies of adsorption, which are the key stimulus components for their adsorption performance. Here, we conclusively review the significance of a less common application of the IGC technique for the physicochemical characterization of metal-organic frameworks (MOFs), which are an innovative subclass of porous materials with matchless properties in terms of structure design and properties. This review focuses on the fundamental theory and instrumentation of IGC as well as its most significant applications in the field of MOF characterization to shed more light on this unique technique.
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