MoS2/MXene Aerogel with Conformal Heterogeneous Interfaces Tailored by Atomic Layer Deposition for Tunable Microwave Absorption

In the design of electromagnetic (EM) wave absorbing materials, it is still a great challenge to optimize the relationship between the attenuation capability and impedance matching synergistically. Herein, a 3D porous MoS2/MXene hybrid aerogel architecture with conformal heterogeneous interface has been built by atomic layer deposition (ALD) based on specific porous templates to optimize the microwave absorption (MA) performance comprehensively. The original porous structure of pristine Ti3C2Tx aerogel used as templates can be preserved well during ALD fabrication, which prolongs the reflection and scattering path and ameliorates the dielectric loss. Meanwhile, plenty of heterointerfaces between MoS2 and Ti3C2Tx have been fabricated based on conformally ALD-deposited MoS2 with controlled thickness on the porous surfaces of the templates, which can effectively optimize the impedance matching and transform its response to EM waves from shielding into absorbing. Moreover, the interaction between the attenuation capability and impedance matching can also be modulated by the number of ALD cycle in MoS2 fabrication. After optimization, MoS2/MXene hybrid aerogel obtained under 300 ALD cycles shows a minimum reflection loss of -61.65 dB at the thickness of 4.53 mm. In addition, its preferable lightweight, high surface area, mechanical, and hydrophobicity properties will also be conducive to further practical applications.

Automated summary

In this study, a 3D porous MoS2/MXene hybrid aerogel structure was constructed by atomic layer deposition (ALD) to optimize the microwave absorption performance. The optimized MoS2/MXene hybrid aerogel showed a minimum reflection loss of -61.65 dB at a thickness of 4.53 mm. Additionally, it had desirable properties such as lightweightness, high surface area, mechanical strength, and hydrophobicity, making it suitable for practical applications.