期刊
ADVANCED ELECTRONIC MATERIALS
卷 8, 期 2, 页码 -出版社
WILEY
DOI: 10.1002/aelm.202100883
关键词
domain structure; ferroelectric polarization; high temperature piezoelectrics; morphotropic phase boundary; multiferroics
资金
- Natural Science Foundation of China [12174299, 51911530125, 51602243]
- China Postdoctoral Science Foundation [2019M663697]
- Ministry of Science and Higher Education of the Russian Federation [0852-2020-0032, BAS0110/20-3-08IF]
- 111 Project of China [B14040]
- U. S. Office of Naval Research (ONR) [N00014-16-1-3106, N00014-12-1-1045]
- Natural Sciences and Engineering Research Council of Canada (NSERC) [RGPIN-2017-06915]
- Shanghai synchrotron radiation facilities (SSRF) beamline [BL02U2]
A simple modified mixed-oxide reaction method was developed to prepare Dy- and Sm-modified BFPT ceramics with significantly improved properties, showing well-saturated ferroelectric hysteresis loops and enhanced piezoelectric properties suitable for high-temperature applications. The enhanced dielectric/piezoelectric properties were mainly attributed to intrinsic mechanisms of polarization rotation/extension, with minimal extrinsic contributions from interphase and domain walls.
Perovskite materials based on BiFeO3-PbTiO3 (BFPT) solid solutions are promising for various applications thanks to the extremely large spontaneous polarization (P-s) and existence of multiferroic morphotropic phase boundary. For applications in piezoelectric and memory devices, complete switching of P-s is needed, which is hard to achieve practically. In this work, a simple modified mixed-oxide reaction method is developed allowing to prepare Dy- and Sm-modified BFPT ceramics with significantly improved properties. The MPB compositions demonstrate well-saturated ferroelectric hysteresis loops with large switchable remanent polarization of 60 mu C cm(-2) and enhanced piezoelectric properties with a large-signal piezoelectric coefficient d(33)* = 214 pm V-1 and a direct piezoelectric coefficient d(33) = 128 pC N-1, which is one and a half times larger than the best d(33) value reported for the BFPT ceramics so far. The Curie temperature reaches 539 degrees C, suggesting a potential for high-temperature applications. The domain structure is studied by piezoresponse force microscopy. It is found that the enhanced dielectric/piezoelectric properties are mainly due to polarization rotation/extension (intrinsic) mechanism, while the extrinsic contributions of the interphase and domain walls are virtually absent. The strategies for improvement of properties of BFPT and related materials are proposed.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据