4.7 Article

Novel Water-Based Paints for Composite Materials Used in Electromagnetic Shielding Applications

期刊

NANOMATERIALS
卷 12, 期 3, 页码 -

出版社

MDPI
DOI: 10.3390/nano12030487

关键词

EMI shielding applications; water based paints; conductive paints; multicomponent nanocomposites; graphene nanoplatelets; polyaniline emeraldine (PANI) doped with poly(styrene sulfonic acid) (PSS) or HCl or HBr; poly(3,4-ethylenedioxythiophene) poly(styrene sulfonic acid)-PEDOT:PSS

资金

  1. NATO Science for Peace and Security (SPS) Programme [G5477]

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The development of eco-friendly conductive water-based paints for EMI-shielding applications was investigated in this study. Graphene nanoplatelets, polyaniline emeraldine doped with poly(styrene sulfonic acid) or HCl or HBr, and poly(3,4-ethylenedioxythiophene) poly(styrene sulfonic acid) were used as components in water-based paints. The optimized compositions resulted in uniform, homogeneous, and conductive layers with good electrical conductivity and efficient EMI-shielding performance.
The development of materials offering electromagnetic interference (EMI) shielding is of significant consideration, since this can help in expanding the lifetime of devices, electromagnetic compatibility, as well as the protection of biological systems. Conductive paints used widely today in electromagnetic interference (EMI) shielding applications are often based on organic solvents that can create safety issues due to the subsequent environment problems. This paper concerned the development of eco-friendly conductive water-based paints for use in EMI-shielding applications. Graphene nanoplatelets, polyaniline emeraldine (PANI) doped with poly(styrene sulfonic acid) (PSS) or HCl or HBr and poly(3,4-ethylenedioxythiophene) poly(styrene sulfonic acid) (PEDOT:PSS) in various ratios were employed in a water base for developing the paints. The target was to develop homogeneous water-based paint-like fluid mixtures easily applied onto surfaces using a paint brush, leading in homogeneous, uniform, opaque layers, draying fast in air at room temperature, and having quite good electrical conductivity that can offer efficient EMI-shielding performance. The results of this parametric trial indicated the optimum compositions leading in paints with optimized properties that can result in uniform, homogeneous, and conductive layers up to a thickness of over 500 mu m without deformation and cracking, offering attenuation of up to 60 dBs of incoming GHz electromagnetic radiation. In addition, the structural and morphological characteristics of these paints were studied in detail.

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