期刊
NANOMATERIALS
卷 12, 期 3, 页码 -出版社
MDPI
DOI: 10.3390/nano12030367
关键词
polyimide film; chemical imidization; graphitization; thermal conductivity
类别
资金
- National Natural Science Foundation of China [21875141, U1760119]
- Science and Technology Commission of Shanghai Municipality [19DZ2271100]
- Shanghai Scientific and Technological Innovation Project [19JC1410400]
- Innovation Program of Shanghai Municipal Education Commission [2019-01-07-00-07-E00015]
With the increasing application of electronic equipment, the need for effective heat dissipation materials is growing. In this study, high thermal conductive graphite films were produced by chemically modifying polyimide films. The results showed that the chemically modified polyimide films had higher strength, thermal stability, and crystal arrangement. The graphite films derived from these modified films exhibited larger crystal size and higher thermal conductivity.
With the large-scale application and high-speed operation of electronic equipment, the thermal diffusion problem presents an increasing requirement for effective heat dissipation materials. Herein, high thermal conductive graphite films were fabricated via the graphitization of polyimide (PI) films with different amounts of chemical catalytic reagent. The results showed that chemically imidized PI (CIPI) films exhibit a higher tensile strength, thermal stability, and imidization degree than that of purely thermally imidized PI (TIPI) films. The graphite films derived from CIPI films present a more complete crystal orientation and ordered arrangement. With only 0.72% chemical catalytic reagent, the graphitized CIPI film achieved a high thermal conductivity of 1767 W center dot m(-1)center dot K-1, which is much higher than that of graphited TIPI film (1331 W center dot m(-1)center dot K-1), with an increase of 32.8%. The high thermal conductivity is attributed to the large in-plane crystallite size and high crystal integrity. It is believed that the chemical imidization method prioritizes the preparation of high-quality PI films and helps graphite films achieve an excellent performance.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据