Efficient and Stable Perovskite Solar Cells Based on Inorganic Hole Transport Materials

Although power conversion efficiencies of organic-inorganic lead halide perovskite solar cells (PSCs) are approaching those of single-crystal silicon solar cells, the working device stability due to internal and external factors, such as light, temperature, and moisture, is still a key issue to address. The current world-record efficiency of PSCs is based on organic hole transport materials, which are usually susceptible to degradation from heat and diffusion of dopants. A simple solution would be to replace the generally used organic hole transport layers (HTLs) with a more stable inorganic material. This review article summarizes recent contributions of inorganic hole transport materials to PSC development, focusing on aspects of device performance and long-term stability. Future research directions of inorganic HTLs in the progress of PSC research and challenges still remaining will also be discussed.

Automated summary

This review article summarizes recent contributions of inorganic hole transport materials to the development of PSCs, focusing on device performance and long-term stability. The importance of stability is highlighted, and a possible solution of replacing organic materials with more stable inorganic materials is proposed.