Optical Properties of V2O5 Thin Films on Different Substrates and Femtosecond Laser-Induced Phase Transition Studied by Pump-Probe Method

Vanadium pentoxide can undergo a reversible phase transition by heating above 260 degrees C; its non-thermal phase transition, as well as ultrafast dynamical processes, is still not known. Here, femtosecond laser-induced phase transition properties in V2O5 thin films were first explored using femtosecond time-resolved pump-probe spectroscopy. The results show that the phase transient processes occur on a 10(-15)-10(-13) temporal scale. The phase transition and recovery properties are dependent on both the substrates and pump laser energy densities. We propose the oxygen vacancies theory to explain the results, and we provide valuable insights into V2O5 films for potential applications.

Automated summary

In this study, the phase transition properties of V2O5 thin films were first explored using femtosecond laser-induced pump-probe spectroscopy. The results show that the phase transition processes occur on an ultrafast timescale and are dependent on the properties of the substrates and the energy density of the pump laser. The proposed oxygen vacancies theory provides valuable insights into potential applications of V2O5 films.