期刊
NANOMATERIALS
卷 11, 期 11, 页码 -出版社
MDPI
DOI: 10.3390/nano11112777
关键词
nano photoelectrocatalysis; urine; hydrogen generation; self-driving; cyclic catalysis of Cl-/Cl; total nitrogen removal
类别
资金
- National Natural Science Foundation of China [22178220, 21875139, 21776177]
- National Key Research and Development Program of China [2018YFE0122300]
- Shanghai International Science and Technology Cooperation Fund Project [18520744900]
A self-driving nano photoelectrocatalytic system was developed to efficiently treat nitrogen pollution in urine, producing hydrogen and removing total nitrogen under neutral pH conditions.
Urine is the main source of nitrogen pollution, while urea is a hydrogen-enriched carrier that has been ignored. Decomposition of urea to H-2 and N-2 is of great significance. Unfortunately, direct urea oxidation suffers from sluggish kinetics, and needs strong alkaline condition. Herein, we developed a self-driving nano photoelectrocatalytic (PEC) system to efficiently produce hydrogen and remove total nitrogen (TN) for urine treatment under neutral pH conditions. TiO2/WO3 nanosheets were used as photoanode to generate chlorine radicals (Cl & BULL;) to convert urea-nitrogen to N-2, which can promote hydrogen generation, due to the kinetic advantage of Cl-/Cl & BULL; cyclic catalysis. Copper nanowire electrodes (Cu NWs/CF) were employed as the cathode to produce hydrogen and simultaneously eliminate the over-oxidized nitrate-nitrogen. The self-driving was achieved based on a self-bias photoanode, consisting of confronted TiO2/WO3 nanosheets and a rear Si photovoltaic cell (Si PVC). The experiment results showed that hydrogen generation with Cl & BULL; is 2.03 times higher than in urine treatment without Cl & BULL;, generating hydrogen at 66.71 mu mol h(-1). At the same time, this system achieved a decomposition rate of 98.33% for urea in 2 h, with a reaction rate constant of 0.0359 min(-1). The removal rate of total nitrogen and total organic carbon (TOC) reached 75.3% and 48.4% in 2 h, respectively. This study proposes an efficient and potential urine treatment and energy recovery method in neutral solution.
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