期刊
MINERALS
卷 12, 期 2, 页码 -出版社
MDPI
DOI: 10.3390/min12020215
关键词
high iron content coal gangue; acid leaching; extraction of aluminum and iron ions; acid leaching kinetic
资金
- Guizhou Provincial Science and Technology Department [[2018]1415]
- Guizhou Provincial Education Department [[2017]054]
- Liupanshui City Science and Technology Foundation [52020-2019-05-17]
- [[2018]1142]
- [2018]1142]
This study investigated the technological conditions and kinetic model of acid leaching aluminum and iron ions from high-iron and low-aluminum coal gangue. The results showed that the leaching ratio of iron ions exceeded 90% and that of aluminum ions exceeded 60% under specific conditions. The leaching behavior of aluminum and iron ions conformed to the mixing control model equation.
Extracting valuable elements from coal gangue is an important method for the utilization of coal gangue. In order to obtain the suitable technological conditions and the acid leaching kinetic model of leaching aluminum and iron ions from high-iron and low-aluminum coal gangue, the effects of calcination temperature, calcination time, and acid types on the leaching results of aluminum and iron ions are studied. The results show that when the gangue is calcined at 675 degrees C for 1 h, then the calcined gangue powder is leached by 6 mol/L hydrochloric acid at 93 degrees C for 4 h, the leaching ratio of iron ions is more than 90%, and that of aluminum ions is more than 60%. Furthermore, the acid leaching kinetic equations at 30 degrees C, 50 degrees C, 70 degrees C, and 90 degrees C are studied by three kinetic models, and the apparent activation energies of the reactions are calculated by the Arrhenius formula. The results show that the leaching behavior of aluminum and iron ions conformed to the mixing control model equation: (1 - x)(-1/3) - 1 + 1/3ln(1 - x) = kt + b. The apparent activation energies of aluminum and iron ions are 55.5 kJ/mol and 55.8 kJ/mol, respectively. All these indicate that the acid leaching process is controlled by the mixing control.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据