Reactive, Sparingly Soluble Calcined Magnesia, Tailor-Made as the Reactive Material for Heavy Metal Removal from Contaminated Groundwater Using Permeable Reactive Barrier

A laboratory method was designed and verified that allows for the testing of alkaline, magnesite-based reactive materials for permeable reactive barriers (PRBs) to remove heavy metals from contaminated groundwater. It was found that caustic calcined magnesia (CCM) with high reactivity and low solubility to remove Cu2+, Zn2+, Ni2+, and Mn2+ cations from mixed aqueous solutions can be prepared by calcination at a suitable temperature and residence time. Regarding the solubility of both the reactive material itself and the precipitates formed, the CCM should contain just a limited content of lime. One way is the calcination of a ferroan magnesite at temperatures above 1000 degrees C. However, the decrease in pH is accompanied by lower efficiency, attributed to the solid-phase reactions of free lime. A different way is the calcination of magnesite under the conditions when CaCO3 is not thermally decomposed. The virtually complete removal of the heavy metals from the model solution was achieved using the CCM characterised by the fraction of carbonates decomposed of approximately 80% and with the highest specific surface area. CCM calcined at higher temperatures could also be used, but this would be associated with higher consumption of crude magnesite. Under the conditions considered in the present work, the product obtained by the calcination at 750 degrees C for 3 h appeared to be optimal. The full heavy metal removal was observed in this case using less magnesite, and, moreover, at a lower temperature (resulting, therefore, in a lower consumption of energy for the calcination and material handling).

Automated summary

A laboratory method was designed and verified for testing alkaline, magnesite-based reactive materials in the removal of heavy metals from contaminated groundwater. Caustic calcined magnesia (CCM) showed high reactivity and low solubility in removing Cu2+, Zn2+, Ni2+, and Mn2+ cations from mixed aqueous solutions. The optimal condition for CCM preparation was found to be calcination at 750 degrees C for 3 hours, achieving full heavy metal removal with lower energy consumption.