Modelling of the Erosive Dissolution of Metal Oxides in a Deep Eutectic Solvent-Choline Chloride/Sulfosalicylic Acid-Assisted by Ultrasonic Cavitation

Here we report on the results concerning the influence of ultrasound on the dissolution process of metal oxides CoO, Ni2O3 and Mn2O3 in choline chloride/sulfosalicylic acid as a deep eutectic solvent. The mechanism of dissolution under cavitation conditions with ultrasonic assistance is described. Theoretical research resulted in equations describing the dissolution process kinetics and linking its basic parameters. Optimal conditions for the most effective ultrasound application were found. Experimental data on dissolution kinetics of metal oxides in deep eutectic solvents was also obtained. It was discovered that experimental data correlates well with theoretical calculations, which confirms the correctness of developing a picture about the physicochemical nature of the process under study.

Automated summary

In this study, the influence of ultrasound on the dissolution process of metal oxides in deep eutectic solvents was investigated. The mechanism of dissolution under cavitation conditions with ultrasonic assistance was described, along with the discovery of optimal conditions for ultrasound application. It was found that experimental data correlated well with theoretical calculations, confirming the accuracy of the physicochemical nature of the process under study.