期刊
MATERIALS HORIZONS
卷 9, 期 1, 页码 121-146出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1mh00809a
关键词
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资金
- City University of Hong Kong
Highly crystalline COFs and CPs are important for improved performance in devices, but achieving this level of crystallinity is challenging. Recent research shows potential ways to enhance crystallinity and design strategies to overcome these challenges.
Highly crystalline covalent organic frameworks (COFs) or conjugated polymers (CPs) are very important and highly desirable because these materials would display better performance in diverse devices and provide more structure-property related information. However, how to achieve highly crystalline or single-crystal COFs and CPs is very challenging. Recently, many research studies have demonstrated the possibility of enhancing the crystallinity of COFs and CPs. Thus, it is timely to offer an overview of the important progress in improving the crystallinity of COFs and CPs from the viewpoint of design strategies. These strategies include polycondensation reaction optimization, improving the planarity, fluorine substitution, side chain engineering, and so on. Furthermore, the challenges and perspectives are also discussed to promote the realization of highly crystalline or single-crystal COFs and CPs.
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