期刊
ENVIRONMENTAL SCIENCE-NANO
卷 9, 期 2, 页码 568-581出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1en01085a
关键词
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资金
- National Natural Science Foundation of China [41931288, 41720104004, 41977277]
- Local Innovation and Entrepreneurship Team Project of Guangdong Special Support Program [2019BT02L218]
- Guangzhou Science and Technology Fund [202102080429]
In this study, the adsorption mechanism of Cr(VI) onto lepidocrocite facets was investigated using various experimental techniques and theoretical calculations. The results showed that rod-like lepidocrocite with a higher proportion of {001}/{010} exhibited higher Cr(VI) adsorption capacity and site density compared to plate-like lepidocrocite. The study also revealed the different surface structures of Cr(VI) on the {001} and {010} facets, which were both thermodynamically stable.
Lepidocrocite, as a ubiquitous iron mineral, is widely detected in different morphologies in natural environments, controlling the mobility and availability of heavy metal ions (HMIs). These different morphologies of lepidocrocite commonly exhibit different surface reactivities due to its exposed facets. However, the adsorption mechanism of HMIs onto lepidocrocite facets remains ambiguous. In this study, Cr(vi) adsorption on lepidocrocite with different exposed facets was investigated via macroscopic batch experiments, synchrotron-based X-ray absorption fine structure (XAFS) spectroscopy, in situ ATR-FTIR spectroscopy, and density functional theory (DFT) calculations. Macroscopic experimental results showed that the maximum Cr(vi) adsorption capacity for rod-like lepidocrocite with a higher proportion of {001}/{010} (R-LEP) was 0.137 mg m(-2), 2.21 times higher than that of plate-like lepidocrocite (P-LEP). Meanwhile, the Cr(vi) site density on the {001} facet was estimated to be 4.30 #Cr nm(-2), much higher than that on the {010} facets (0.42 #Cr nm(-2)). The fitting results of EXAFS spectroscopy revealed that Cr(vi) coordinated to the surfaces of P-LEP and R-LEP via the formation of both bidentate and monodentate inner-sphere complexes. In situ ATR-FTIR spectroscopy combined with theoretical frequency calculations showed that two Cr(vi) species formed in different relative proportions on P-LEP and R-LEP, the bidentate binuclear complex was the dominant species on the {001} facets, and the protonated monodentate binuclear configuration formed on the {010} facets. DFT+U calculations further confirmed that the two Cr(vi) surface structures on their corresponding facets both exhibited high thermodynamic stability. This study will help to understand the roles of lepidocrocite in mobilization of HMIs in environments and provide guidance to design an efficient adsorbent for environmental remediation.
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