Ultrathin Bi4O5Br2 nanosheets with surface oxygen vacancies and strong interaction with Bi2O2CO3 for highly efficient removal of water contaminants

Ultrathin Bi4O5Br2 nanosheets with about a 10 nm thickness were synthesized by in situ intergrowth with Bi2O2CO3 sheets at room temperature. The degradation rates of organic pollutants on the catalyst were 28.1, 9.5, and 8.5 times higher than those on P25, N-TiO2 and 50 nm thick Bi4O5Br2 under a visible LED. The supreme catalytic activity was confirmed to be due to the significantly enhanced charge separation and transfer by surface oxygen vacancies on the ultrathin nanosheets, and the facilitated adsorption-degradation process at the solid-liquid micro-interface. The photogenerated electrons were demonstrated to be trapped on surface OVs to reduce surface adsorbed O-2 into O-2(-). Meanwhile, the photogenerated holes were effectively utilized to directly oxidize organic pollutants at the catalyst surface. FTIR, HPLC-Q-TOF-MS and IC analysis confirmed that diclofenac (DCF) was degraded at the catalyst surface through decarboxylation, dechloridation and C-N cleavage, and further mineralized in reaction solution. In addition, the developed catalyst can work at different pH values (5-10) and was stable after eight reaction cycles, showing good potential in practical application.

Automated summary

Ultrathin Bi4O5Br2 nanosheets with about a 10 nm thickness were successfully synthesized by in situ intergrowth with Bi2O2CO3 sheets at room temperature. The significantly enhanced charge separation and transfer by surface oxygen vacancies on the ultrathin nanosheets, and the facilitated adsorption-degradation process at the solid-liquid micro-interface were confirmed to contribute to the superior catalytic activity. The developed catalyst showed a greatly increased degradation rate of organic pollutants under a visible LED, and exhibited stability and potential for practical application.