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Recent Advances in Enhanced Performance of Ni-Rich Cathode Materials for Li-Ion Batteries: A Review

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ENERGY TECHNOLOGY
卷 10, 期 3, 页码 -

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WILEY-V C H VERLAG GMBH
DOI: 10.1002/ente.202100775

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coating; degradation mechanisms; doping; Ni-rich cathode materials

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Ni-rich cathode materials have been recognized for their advantages in high energy Li-ion batteries, but their commercialization is hindered by electrochemical cycling issues. Various methods such as doping, coating, and comodification have been adopted to overcome these challenges.
High energy Li-ion batteries (LIBs) have garnered substantial consideration in recent years for their utilization in many fields like communication, transportation, and aviation. As the cathode is the crucial component of LIBs, so by enhancing its electrochemical performance, the capacity, rate capability, as well as cyclability of batteries can be enhanced. Ni-rich cathode materials (LiNi x Mn y Co1-x-y O2, x >= 0.5) have been accredited for their benefits in enhanced capacity, high working voltage, and low manufacturing cost. The high Ni content is accountable for the exceptional capacity but the utilization in the commercialized LIBs is mired by their electrochemical cycling issues like capacity fading, voltage decay, and safety hazard. To overcome these obstructions, a variety of methodologies have been adopted like doping, coating, and comodification of these cathode materials. An inclusive study of Ni-rich cathode materials, their degradation mechanism, and the strategies is conferred, which have been employed in recent years to overcome the challenges faced by these materials in their commercialization.

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