期刊
SYMMETRY-BASEL
卷 14, 期 2, 页码 -出版社
MDPI
DOI: 10.3390/sym14020326
关键词
alkanes; chirality; cyclodextrin; ExoMars; gas chromatography; isoprenoids; MOMA
资金
- ANR, UCAJEDI [ANR-15-IDEX-01, ANR-16-CE29-0015, ANR-18-CE29-004]
Gas chromatography was used to separate acyclic saturated hydrocarbon enantiomers, and the absolute stereochemical configuration was determined through the synthesis of single enantiomers. The study highlights the significance of chiral hydrocarbons and their potential use as biosignatures in geological and astrobiology studies. Additionally, the findings have implications for the search for life on Mars by the ESA's ExoMars rover in 2023.
Acyclic saturated hydrocarbon enantiomers were resolved by gas chromatography using a beta-cyclodextrin-based chiral stationary phase. The stereospecific synthesis of single enantiomers of 4-methyloctane allowed to assign the absolute stereochemical configuration to the resolved enantiomers. Data show that the (S)-4-methyloctane shows higher chromatographic retention as compared to the (R)-4-methyloctane due to stronger van der Waals interactions with the beta-cyclodextrin chiral selector. This introductive research presents future prospects for the separation of stereoisomers of larger branched hydrocarbons. We discuss the importance of chiral hydrocarbons, more precisely the stereochemistry of the isoprenoid alkanes pristane and phytane, as potential biosignatures stable on geological timescales. The origins of pristane and phytane in Earth sediments are presented, and we detail the implications for the search of extinct or extant life on Mars. The data presented here will help to systematically investigate the chirality of hydrocarbon enantiomers in biological and nonbiological samples and in samples to be analyzed by the ESA's ExoMars rover to trace the chiral precursors of life in 2023.
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