期刊
NANO ENERGY
卷 92, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.nanoen.2021.106760
关键词
Li-rich; Co-free; Cathode materials; Coating; Doping; Eutectic melting salt
类别
资金
- project of International Science & Technology Cooperation of China [2019YFE0100200]
A novel eutectic melting salt treatment strategy was developed to improve the performance of cobalt-free iron-substituted Li-ion battery cathode materials by introducing a robust fluoride coating layer and functional doping. This approach effectively enhanced the electrochemical performance of the cathode, with negligible capacity loss, mitigated voltage fading, improved rate capability, and better thermal stability.
Lithium-rich layered oxides (LLOs) are one of the most promising cathodes for next-generation Li-ion batteries owing to their extraordinary energy density and low cost. However, the anionic redox reactions inevitably destabilize the oxygen framework and lead to oxygen release, which incurs voltage fading and capacity decay. Although less voltage fading can be realized in the cobalt-free iron-substituted materials, they still suffer from severe transition metal (TM) dissolution and poor kinetics. Herein, to ameliorate these drawbacks, we develop a novel eutectic melting salt treatment strategy. By controlling the melt and solidification of a LiF-MgF2-CaF2 ternary salt, the robust fluoride coating layer and functional doping were synchronously conducted in a Co-free Fe-substituted Li-rich cathode Li1.2Ni0.13Fe0.13Mn0.54O2. The outer fluoride layer effectively suppresses the oxygen release and prevents TM ion dissolution, while the inner doping elements improve the Li+ diffusion kinetics and further stabilize the bulk crystal structure. Benefiting from these, the modified cathode exhibits significantly enhanced electrochemical performance, with negligible capacity loss from the 35th to the 120th cycles at 0.2 C, mitigated voltage fading, improved rate capability and better thermal stability as well.
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