4.6 Article

Combining electrochemical and quantitative elemental analysis to investigate the sulfur poisoning process of ceria thin film fuel electrodes

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Summary: Ceria-containing electrodes offer superior ionic and electronic conductivities compared to current cermet alloys, making them ideal for dry hydrocarbon fuel and CO2 electrolysis applications. Anodes with a single phase gadolinia doped ceria functional layer perform even better than cermets, but must address the drawback of lower electronic conductivity. By adjusting temperature, thickness, and atmosphere, the polarization resistance of GDC anodes can be divided into ohmic, electrochemical, and gas diffusion contributions. At 800 degrees C, the electrode has extremely low ohmic resistance, even with low H2 and H2O pressures and significant gas phase diffusion kinetics.

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