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Electrospun metal-organic framework based nanofibers for energy storage and environmental applications: current approaches and challenges

期刊

JOURNAL OF MATERIALS CHEMISTRY A
卷 10, 期 4, 页码 1642-1681

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/d1ta08413e

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资金

  1. National Key RAMP
  2. D Program of China [2020YFF0413818]
  3. Project of Liaoning Province, China [0518XN011, 0519BS014]
  4. National Natural Science Foundation of China [21671025, 21471021]
  5. Innovation and Entrepreneurship Training Project of Liaoning Province, China [202010167019, S202010167045, S202010167046]

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In recent years, research on MOF based composite nanofibers has seen significant development and application in energy storage and environmental protection fields, offering an effective route to broaden the practical applications of MOFs. However, challenges still exist in this area that need to be addressed for future research directions to be determined.
In recent years, a great deal of investigation has been performed based on the study of metal-organic frameworks (MOFs) combined with other materials, in order to overcome the tremendous challenge encountered by single MOFs in practical applications. Among them are MOF based composite nanofibers prepared via electrospinning with the advantages of inorganic porous materials and polymeric nanofibers, which have witnessed intensive development and extensive applications in energy storage and environment conservation fields. Beyond that, preparing MOF based composite nanofibers is also considered to be an effective route to broaden the practical application of MOFs. Herein, a comprehensive review of the recent developments of MOF based composite nanofibers prepared via the electrospinning process, serving as functional materials, is provided. From the perspective of fabrication, the major routes reported so far for fabricating MOF based composite nanofibers are first systematically discussed. Furthermore, the fundamental applications of MOF based composite nanofibers in energy storage and environmental protection are introduced in detail. Finally, a series of critical challenges in the above research area, and some directions for future research are put forward.

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