期刊
JOURNAL OF MATERIALS CHEMISTRY A
卷 10, 期 9, 页码 4770-4781出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1ta09547a
关键词
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资金
- Australian Research Council [IH140100018, FT130100380, DP180100094]
- Deakin University
- Australian Research Council [FT130100380] Funding Source: Australian Research Council
This study demonstrates that the addition of cellulose nanocrystals (CNCs) can induce liquid crystal (LC) phases in dilute MXene dispersions, even at concentrations significantly below its own LC threshold. This approach lowers the concentration and size threshold for MXene solution processing into robust macro-architectures and improves the properties of LC-MXene fibers.
The liquid crystal (LC) phases of two-dimensional (2D) transition metal carbides/nitrides (MXenes) have enabled the production of their unique macro-architectures with an ordered microstructure and enhanced properties. However, LC phases in additive-free MXene dispersions are known to occur above relatively high sheet size and concentration thresholds, which can be difficult to obtain and process. Easily prepared non-LC MXene dispersions composed of small sheets at low concentrations on the other hand, do not possess adequate rheological properties to form desired macro-architectures. Here, we report that LC phases in dilute MXene dispersions can be induced by adding cellulose nanocrystals (CNCs), even at concentrations significantly below its own LC threshold. The favorable mutual interaction lowers the concentration and size threshold for MXene solution processing into robust superior macro-architectures, and improves the properties of LC-MXene fibers produced at conventional concentrations (similar to 30 mg mL(-1)). As an example, fibers wet-spun from 10 mg mL(-1) LC CNC-MXene containing 75% MXene (M-75), exhibit high tensile strength (similar to 60 MPa), conductivity (similar to 3000 S cm(-1)), and volumetric capacitance (similar to 950 F cm(-3)), in contrast to 10 mg mL(-1) pure MXene (M-100), which was unspinnable. The synergistic improvements brought by CNCs on LC formation may be extended to mixed dispersions of other nanomaterials and is anticipated to further broaden the array of solution processing of MXenes into functional architectures and devices.
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