4.6 Article

Regulating the Alkalinity of Carbon Nitride by Magnesium Doping to Boost the Selective Isomerization of Glucose to Fructose

相关参考文献

注意:仅列出部分参考文献,下载原文获取全部文献信息。
Article Chemistry, Physical

Synthesis of MgO-doped ordered mesoporous carbons by Mg2+-tannin coordination for efficient isomerization of glucose to fructose

Junyan Fu et al.

Summary: In-situ MgO-doped ordered mesoporous carbon (OMC@MgO) was fabricated using a formaldehyde-free self-assembly method, with biomass-derived tannin as the carbon precursor and Mg2+ as the cross-linker and catalyst precursor. The OMC@MgO exhibited well-controlled mesoporous structures, high surface area, and good catalytic activity, achieving a high fructose yield with good selectivity from glucose. It also showed tolerance to high glucose concentrations and maintained recyclability.

GREEN ENERGY & ENVIRONMENT (2023)

Article Engineering, Environmental

Energy efficient production of 5-hydroxymethylfurfural (5-HMF) over surface functionalized carbon superstructures under microwave irradiation

Xiaoqi Lyu et al.

Summary: The study developed a MW-responsive catalyst for efficient conversion of fructose to 5-HMF under MW irradiation. The system exhibited high conversion rate, selectivity, recyclability, and significantly higher energy efficiency compared to conventional heating systems.

CHEMICAL ENGINEERING JOURNAL (2022)

Article Chemistry, Multidisciplinary

Critical factors for levulinic acid production from starch-rich food waste: solvent effects, reaction pressure, and phase separation

Shanta Dutta et al.

Summary: This study explores the catalytic production of levulinic acid (LA) from bread waste, with bio-derived and CO2-derived green solvents evaluated for LA synthesis. The use of a biphasic system significantly increased LA yield, providing insights for high-performance LA production and extraction. These findings contribute to the development of sustainable biorefinery processes.

GREEN CHEMISTRY (2022)

Article Chemistry, Multidisciplinary

Roles of Ball Milling Pretreatment and Titanyl Sulfate in the Synthesis of 5-Hydroxymethylfurfural from Cellulose

Qidong Hou et al.

Summary: This study shows that ball milling pretreatment can greatly facilitate the conversion of cellulose to HMF, resulting in a significant increase in yield. Phosphorylated titanium dioxide is also found to have high HMF yield, demonstrating the potential of Ti-based heterogeneous catalysts.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2022)

Article Chemistry, Physical

One-step hydrothermal synthesis of CdxInyS(x+1.5y) for photocatalytic oxidation of biomass-derived 5-hydroxymethylfurfural to 2, 5-diformyl-furan under ambient conditions

Ming Zhang et al.

Summary: In this study, Cd-rich CdxInyS(x+1.5y) catalysts with Cd:In ratios exceeding 1:2 were controllably synthesized, showing excellent photocatalytic performance in the oxidation of HMF to DFF. The CdS nanorods in the catalyst effectively promote the separation of photoexcited electron-hole pairs and enable transboundary transfer of photogenerated carriers, indicating great potential of cadmium-indium sulfides as photocatalysts for biomass conversion under ambient conditions.

APPLIED CATALYSIS B-ENVIRONMENTAL (2022)

Article Chemistry, Physical

Selective oxidation of glucose to gluconic acid and glucaric acid with chlorin e6 modified carbon nitride as metal-free photocatalyst

Xinyu Bai et al.

Summary: Here, we report a metal-free photocatalyst consisting of BNCN and Ce6, which can efficiently and selectively oxidize glucose into gluconic acid and glucaric acid. The introduction of nitrogen defects and optimization of optical absorption have significantly enhanced the total selectivity of the photocatalytic system.

APPLIED CATALYSIS B-ENVIRONMENTAL (2022)

Article Chemistry, Physical

Photocatalytic conversion of biomass-based monosaccharides to lactic acid by ultrathin porous oxygen doped carbon nitride

Jiliang Ma et al.

Summary: The application of photocatalysis in biorefinery is significant for sustainable development, with oxygen atom doped Ut-OCN as an efficient catalyst for lactic acid production. The photocatalyst shows high activity and stability, paving the way for lactic acid production via photocatalysis.

APPLIED CATALYSIS B-ENVIRONMENTAL (2021)

Article Chemistry, Physical

Oxygen-doped crystalline carbon nitride with greatly extended visible-light-responsive range for photocatalytic H2 generation

Guoqiang Zhang et al.

Summary: A series of oxygen-doped K+ implanted CCN (KCN) materials were successfully prepared, exhibiting a wider photoresponse range for visible and near-infrared light absorption, leading to improved solar energy utilization. The oxygen doping strategy in KCN resulted in significantly enhanced H-2 generation, with a maximum active wavelength of 650 nm, presenting clear advantages over other CCN-based photocatalysts.

APPLIED CATALYSIS B-ENVIRONMENTAL (2021)

Article Chemistry, Physical

Reasonable regulation of carbon/nitride ratio in carbon nitride for efficient photocatalytic reforming of biomass-derived feedstocks to lactic acid

Jiliang Ma et al.

Summary: Carbon nitride photocatalyst with a controllable C/N ratio shows promising potential in selective synthesis of lactic acid from biomass-derived monosaccharides. The catalyst exhibits excellent visible light absorption ability and mobility of photogenerated carriers, leading to high efficiency in lactic acid production. Additionally, the photocatalyst demonstrates excellent reusability and universality, making it a suitable candidate for industrial production.

APPLIED CATALYSIS B-ENVIRONMENTAL (2021)

Article Chemistry, Multidisciplinary

On-Surface Polymerization of In-Plane Highly Ordered Carbon Nitride Nanosheets toward Photocatalytic Mineralization of Mercaptan Gas

Fangsong Guo et al.

Summary: 2D carbon nitride nanosheets with in-plane highly ordered structure (PCNNs-IHO) are successfully prepared by on-surface polymerization of melamine on NaCl crystal surface at elevated temperatures. The NaCl crystals with relative high surface energy facilitate the adsorption and activation of melamine to undergo condensation reaction, and also function as unique substrates to orientate the assembly of 2D nanosheet structure. NaCl acts as a reactant to provide Na+ doping into carbon nitride matrix, affording PCNNs-IHO with robust structural base sites. PCNNs-IHO exhibits superior photocatalytic performance toward CH3SH mineralization under visible light irradiation.

ADVANCED MATERIALS (2021)

Article Chemistry, Multidisciplinary

Atomically Dispersed s-Block Magnesium Sites for Electroreduction of CO2 to CO

Qiyou Wang et al.

Summary: This study demonstrates the construction of atomically dispersed magnesium atoms embedded in graphitic carbon nitride for CO2 electroreduction to CO. Theoretical calculations and experimental results show that the desorption of CO on Mg sites is easier compared to Fe and Co sites, leading to higher CO Faradaic efficiency and activity. This work sheds new light on the use of s-block metal sites for efficient CO2RR.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Article Green & Sustainable Science & Technology

Recent advance on the catalytic system for efficient production of biomass-derived 5-hydroxymethylfurfural

Di Hu et al.

Summary: This review assesses the recent advances in HMF production, with a main focus on the function of catalysts, solvent systems, and reactors. It summarizes and compares the general overview of HMF production, the correlation between the physicochemical properties of catalysts, with special attention on acidity, and the catalytic activity under various reaction parameters.

RENEWABLE & SUSTAINABLE ENERGY REVIEWS (2021)

Article Chemistry, Physical

Solar-Driven Glucose Isomerization into Fructose via Transient Lewis Acid-Base Active Sites

Jiu Wang et al.

Summary: The research demonstrates an effective strategy for fast sunlight-driven glucose isomerization with over 60% fructose selectivity, achieved through a rationally designed crystalline carbon nitride. This provides a new photocatalytic process for biofuels and chemicals production.

ACS CATALYSIS (2021)

Article Chemistry, Multidisciplinary

γ-Valerolactone-introduced controlled-isomerization of glucose for lactic acid production over an Sn-Beta catalyst

Xinpeng Zhao et al.

Summary: The study revealed that GVL can effectively suppress the conversion of glucose into fructose during catalytic reactions, leading to a higher yield of lactic acid. This research provides new insights for controlling the hydrothermal conversion of glucose into lactic acid.

GREEN CHEMISTRY (2021)

Article Chemistry, Multidisciplinary

Effective Dispersion of MgO Nanostructure on Biochar Support as a Basic Catalyst for Glucose Isomerization

Season S. Chen et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2020)

Article Chemistry, Multidisciplinary

Solvent-Activated Hafnium-Containing Zeolites Enable Selective and Continuous Glucose-Fructose Isomerisation

Luca Botti et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Article Green & Sustainable Science & Technology

Transformation of carbohydrates to 5-hydroxymethylfurfural with high efficiency by tandem catalysis

Yifan Nie et al.

JOURNAL OF CLEANER PRODUCTION (2020)

Article Chemistry, Physical

Selective Glucose-to-Fructose Isomerization in Ethanol Catalyzed by Hydrotalcites

Mizuho Yabushita et al.

ACS CATALYSIS (2019)

Article Chemistry, Multidisciplinary

Crab Shell-Derived Lotus Rootlike Porous Carbon for High Efficiency lsomerization of Glucose to Fructose under Mild Conditions

Feng Shen et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2019)

Article Chemistry, Multidisciplinary

Tin-Functionalized Wood Biochar as a Sustainable Solid Catalyst for Glucose Isomerization in Biorefinery

Xiao Yang et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2019)

Article Chemistry, Multidisciplinary

Macroporous Niobium Phosphate-Supported Magnesia Catalysts for Isomerization of Glucose-to-Fructose

Da-Ming Gao et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2019)

Article Chemistry, Multidisciplinary

Metalated carbon nitrides as base catalysts for efficient catalytic hydrolysis of carbonyl sulfide

Fangsong Guo et al.

CHEMICAL COMMUNICATIONS (2019)

Review Chemistry, Multidisciplinary

Advances in porous and nanoscale catalysts for viable biomass conversion

Putla Sudarsanam et al.

CHEMICAL SOCIETY REVIEWS (2019)

Article Materials Science, Multidisciplinary

Facile preparation of Mg-doped graphitic carbon nitride composites as a solid base catalyst for Knoevenagel condensations

Qingfang Deng et al.

JOURNAL OF MATERIALS SCIENCE (2018)

Article Chemistry, Physical

Desilicated NaY zeolites impregnated with magnesium as catalysts for glucose isomerisation into fructose

I. Graca et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2018)

Article Chemistry, Multidisciplinary

Carbohydrate stabilization extends the kinetic limits of chemical polysaccharide depolymerization

Ydna M. Questell-Santiago et al.

NATURE CHEMISTRY (2018)

Article Chemistry, Multidisciplinary

Isomerization of Glucose into Fructose over Natural and Synthetic MgO Catalysts

Asimina A. Marianou et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2018)

Article Chemistry, Multidisciplinary

Selective Glucose Isomerization to Fructose via a Nitrogen-doped Solid Base Catalyst Derived from Spent Coffee Grounds

Season S. Chen et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2018)

Review Chemistry, Multidisciplinary

Catalytic Conversion of Carbohydrates to Initial Platform Chemicals: Chemistry and Sustainability

Laszlo T. Mika et al.

CHEMICAL REVIEWS (2018)

Review Chemistry, Multidisciplinary

Organic Solvent Effects in Biomass Conversion Reactions

Li Shuai et al.

CHEMSUSCHEM (2016)

Review Chemistry, Multidisciplinary

Heterogeneously Catalyzed Hydrothermal Processing of C5-C6 Sugars

Xingguang Zhang et al.

CHEMICAL REVIEWS (2016)

Review Chemistry, Multidisciplinary

Catalytic Isomerization of Biomass-Derived Aldoses: A Review

Irina Delidovich et al.

CHEMSUSCHEM (2016)

Article Chemistry, Multidisciplinary

Fructose production via extraction-assisted isomerization of glucose catalyzed by phosphates

Irina Delidovich et al.

GREEN CHEMISTRY (2016)

Article Chemistry, Physical

Methyl-ligated tin silsesquioxane catalyzed reactions of glucose

Stephen K. Brand et al.

JOURNAL OF CATALYSIS (2016)

Article Chemistry, Multidisciplinary

Self-Pillared, Single-Unit-Cell Sn-MFI Zeolite Nanosheets and Their Use for Glucose and Lactose Isomerization

Limin Ren et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2015)

Article Chemistry, Physical

Post-synthesis Snβ: An exploration of synthesis parameters and catalysis

Jan Dijkmans et al.

JOURNAL OF CATALYSIS (2015)

Article Biochemistry & Molecular Biology

Promotion or suppression of glucose isomerization in subcritical aqueous straight- and branched-chain alcohols

Da-Ming Gao et al.

BIOSCIENCE BIOTECHNOLOGY AND BIOCHEMISTRY (2015)

Article Chemistry, Physical

Selective Base-Catalyzed Isomerization of Glucose to Fructose

Chi Liu et al.

ACS CATALYSIS (2014)

Article Chemistry, Physical

Active Sites in Sn-Beta for Glucose Isomerization to Fructose and Epimerization to Mannose

Ricardo Bermejo-Deval et al.

ACS CATALYSIS (2014)

Article Chemistry, Multidisciplinary

Efficient Isomerization of Glucose to Fructose over Zeolites in Consecutive Reactions in Alcohol and Aqueous Media

Shunmugavel Saravanamurugan et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2013)

Article Chemistry, Physical

mpg-C3N4 as a solid base catalyst for Knoevenagel condensations and transesterification reactions

Fangzheng Su et al.

CATALYSIS SCIENCE & TECHNOLOGY (2012)

Article Multidisciplinary Sciences

Tin-containing zeolites are highly active catalysts for the isomerization of glucose in water

Manuel Moliner et al.

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2010)