4.6 Article

Direct Solar Energy-Mediated Synthesis of Tertiary Benzylic Alcohols Using a Metal-Free Heterogeneous Photocatalyst

相关参考文献

注意:仅列出部分参考文献,下载原文获取全部文献信息。
Article Chemistry, Organic

Photocatalysis: A Green Tool for Redox Reactions

Robin Cauwenbergh et al.

Summary: Reduction-and-oxidation (redox) reactions are crucial for the synthesis of value-added compounds, and the emerging field of photoredox catalysis utilizes visible light for oxidation or reduction processes. This tutorial paper provides an introduction to the basics of photoredox catalysis and limited examples to stimulate further research in this growing area.

SYNLETT (2022)

Article Chemistry, Physical

Photocatalytic (Het)arylation of C(sp3)-H Bonds with Carbon Nitride

Saikat Das et al.

Summary: Graphitic carbon nitride materials have shown potential in synthetic photocatalysis for direct arylation of C(sp(3))-H bonds, with a broad synthetic scope and high selectivity. The unique energy-transfer process (EnT) from the organic semiconductor to the nickel complex enables diverse applications, including late-stage functionalization of drugs.

ACS CATALYSIS (2021)

Article Chemistry, Physical

Atomic-Level Understanding for the Enhanced Generation of Hydrogen Peroxide by the Introduction of an Aryl Amino Group in Polymeric Carbon Nitrides

Tong Zhang et al.

Summary: A comprehensive study on a modified PCN revealed its high efficiency in H2O2 production and identified possible active catalytic sites using a combination of techniques.

ACS CATALYSIS (2021)

Review Chemistry, Multidisciplinary

Molecular oxygen-mediated oxygenation reactions involving radicals

Conghui Tang et al.

Summary: Molecular oxygen, as a green and non-toxic oxidant, offers various advantages in organic transformations for the synthesis of oxygen-containing compounds. Recent advances in radical processes using molecular oxygen as an oxidant have been discussed, along with reaction scopes, limitations, and mechanisms, providing insights for future developments in this field.

CHEMICAL SOCIETY REVIEWS (2021)

Review Chemistry, Multidisciplinary

Photochemical reduction of carbon dioxide to formic acid

Robin Cauwenbergh et al.

Summary: With the increasing awareness of green chemistry, carbon capture and utilization (CCU) has gained more attention compared to carbon capture and storage (CCS). Sustainable methods for converting CO2 into valuable products have become popular and important for society. This review specifically focuses on the production of formic acid using homogeneous catalysts under photocatalytic conditions, aiming to stimulate further research in this rapidly growing field.

GREEN CHEMISTRY (2021)

Review Chemistry, Multidisciplinary

Oxidase reactions in photoredox catalysis

Nicholas L. Reed et al.

Summary: The nature of the terminal oxidant in oxidation reactions plays a crucial role in determining the mechanism, efficiency, and practicality of a synthetic protocol. Photoredox catalysis has seen success in oxygenase-type reactions, while progress in photocatalytic oxidase reactions has been slower. This review highlights key classes of terminal oxidants used in photoredox oxidase transformations and their mechanistic features and benefits.

CHEMICAL SOCIETY REVIEWS (2021)

Article Chemistry, Multidisciplinary

Nature inspired singlet oxygen generation to access α-amino carbonyl compounds via 1,2-acyl migration

Waldemar Schilling et al.

Summary: Chlorophyll catalyzes chemical reactions to directly produce alpha-amino carbonyl compounds from enaminones. Singlet oxygen generated during photosynthesis can react with unsaturated double bonds, facilitating the synthesis of valuable compounds. The photosensitizer used in this research is cheap, commercially available, and provides high efficiency for singlet oxygen mediated chemistry.

GREEN CHEMISTRY (2021)

Article Chemistry, Applied

Chemoselective Tertiary C-H Hydroxylation for Late-Stage Functionalization with Mn(PDP)/Chloroacetic Acid Catalysis

Rachel K. Chambers et al.

ADVANCED SYNTHESIS & CATALYSIS (2020)

Article Chemistry, Multidisciplinary

Visible-Light-Mediated Dearomatisation of Indoles and Pyrroles to Pharmaceuticals and Pesticides

Waldemar Schilling et al.

CHEMISTRY-A EUROPEAN JOURNAL (2020)

Review Multidisciplinary Sciences

Designing for a green chemistry future

Julie B. Zimmerman et al.

SCIENCE (2020)

Article Chemistry, Organic

Kinetics of N-oxyl Radicals' Decay

Olga Kushch et al.

JOURNAL OF ORGANIC CHEMISTRY (2020)

Review Chemistry, Multidisciplinary

Metal-Free Photocatalysts for C-H Bond Oxygenation Reactions with Oxygen as the Oxidant

Yu Zhang et al.

CHEMSUSCHEM (2019)

Article Chemistry, Multidisciplinary

Mild and Practical Dirhodium(II)/NHPI-Mediated Allylic and Benzylic Oxidations with Air as the Oxidant

Yi Wang et al.

CHEMISTRY-A EUROPEAN JOURNAL (2019)

Review Chemistry, Multidisciplinary

Photocatalytic Oxygenation Reactions Using Water and Dioxygen

Shunichi Fukuzumi et al.

CHEMSUSCHEM (2019)

Article Chemistry, Multidisciplinary

Synthesis of Benzylic Alcohols by C-H Oxidation

Lalita Tanwar et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

Article Chemistry, Multidisciplinary

Direct Oxidation of Csp3-H bonds using in Situ Generated Trifluoromethylated Dioxirane in Flow

Mathieu Lesieur et al.

CHEMISTRY-A EUROPEAN JOURNAL (2019)

Article Chemistry, Multidisciplinary

Bicontinuous mesoporous Co, N co-doped carbon catalysts with high catalytic performance for ethylbenzene oxidation

Lushuang Zhang et al.

NEW JOURNAL OF CHEMISTRY (2019)

Article Chemistry, Physical

Heterogeneous Organocatalysis for Photoredox Chemistry

Aleksandr Savateev et al.

ACS CATALYSIS (2018)

Article Chemistry, Multidisciplinary

Scalable, Electrochemical Oxidation of Unactivated C-H Bonds

Yu Kawamata et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

Article Chemistry, Multidisciplinary

Discriminating Catalytically Active FeNx Species of Atomically Dispersed Fe-N-C Catalyst for Selective Oxidation of the C-H Bond

Wengang Liu et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

Article Chemistry, Multidisciplinary

Eutectic Syntheses of Graphitic Carbon with High Pyrazinic Nitrogen Content

Nina Fechler et al.

ADVANCED MATERIALS (2016)

Article Chemistry, Multidisciplinary

Graphitic Carbon Nitride Polymers toward Sustainable Photoredox Catalysis

Yun Zheng et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2015)

Article Chemistry, Multidisciplinary

Catalyst-Controlled Aliphatic C-H Oxidations with a Predictive Model for Site-Selectivity

Paul E. Gormisky et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2013)

Article Chemistry, Multidisciplinary

Co-Monomer Control of Carbon Nitride Semiconductors to Optimize Hydrogen Evolution with Visible Light

Jinshui Zhang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2012)

Article Chemistry, Multidisciplinary

Diverting non-haem iron catalysed aliphatic C-H hydroxylations towards desaturations

Marinus A. Bigi et al.

NATURE CHEMISTRY (2011)

Article Chemistry, Medicinal

2-Acetylpyridine thiosemicarbazones: Cytotoxic activity in nanomolar doses against malignant gliomas

Josane A. Lessa et al.

EUROPEAN JOURNAL OF MEDICINAL CHEMISTRY (2010)