Facile Synthesis of MOFs-Templated Carbon Aerogels with Enhanced Tetracycline Adsorption Performance

Three-dimensional aerogels have great potential for antibiotic removal from aqueous solution due to their excellent solution mass transfer channels and special morphology. Herein, the metal ions were bound with alginate to form alginate-Fe, alginate-Cu, and alginate-Fe-Cu hydrogels, then they were used as nucleation sites for metal organic framework (MOF) growth to obtain MAlgs gels, respectively. Considering the aqueous environmental stability of MOFs particles, the alginate and MOF particles in MAlgs aerogels were pyrolyzed as templates to obtain the derived carbon aerogel CMAlgs. The results showed that the adsorption capacity of MAlgs-Fe-Cu aerogel was higher than that of MAlg-Cu and MAlg-Fe aerogels, up to ~130 mg center dot g(-1). The adsorption performance of carbon aerogel CMAlg-Cu decreased obviously because of the decrease of pore size and oxygen-containing functional groups. The adsorption process is a combination of physical adsorption and chemical adsorption. In addition, CMAlgs aerogels exhibit better recyclability than MAlgs aerogels. This work provides a new strategy for fabricating MOFs-templated in-situ grown carbon aerogels for water purification.

Automated summary

In this study, three-dimensional aerogels were utilized as templates for the in-situ growth of MOFs and derived carbon aerogels, which showed excellent adsorption capacity for antibiotic removal from aqueous solution. The research provides a new strategy for water purification.