Analysis of the Damage Mechanism around the Crack Tip for Two Rubber-Toughened PLA-Based Blends

The toughening mechanisms of poly(lactic acid; PLA) blended with two different elastomers, namely poly (butylene adipate-co-terephtalate; PBAT) and polyolefin elastomers with grafted glycidyl methacrylate (POE-g-GMA), at 10 and 20 wt.%, were investigated. Tensile and Charpy impact tests showed a general improvement in the performance of the PLA. The morphology of the dispersed phases showed that PBAT is in the form of spheres while POE-g-GMA has a dual sphere/fibre morphology. To correlate the micromechanical deformation mechanism with the macroscopical mechanical behaviour, the analysis of the subcritical crack tip damaged zone of double-notched specimens subjected to a four-point bending test (according to the single-edge double-notch four-point bend (SEDN-4PB) technique) was carried out using several microscopic techniques (SEM, polarized TOM and TEM). The damage was mainly generated by shear yielding deformation although voids associated with dilatational bands were observed.

Automated summary

The study investigated the toughening mechanisms of poly(lactic acid; PLA) blended with two different elastomers, PBAT and POE-g-GMA, showing an improvement in PLA performance. PBAT appeared as spheres while POE-g-GMA had a dual sphere/fibre morphology. Damage was mainly generated by shear yielding deformation in the subcritical crack tip damaged zone.