4.5 Review

Chiral Expression and Morphology Control in Polymer Dispersion Systems

期刊

CHEMPLUSCHEM
卷 87, 期 5, 页码 -

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/cplu.202100556

关键词

chirality; polymer dispersions; polymers; self-assembly; supramolecular chemistry

资金

  1. National Nature Science Foundation of China [92056111, 21971180]
  2. Nature Science Key Basic Research of Jiangsu Province for Higher Education [19KJA360006]
  3. Priority Academic Program Development (PAPD) of Jiangsu Higher Education Institutions
  4. Program of Innovative Research Team of Soochow University

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This review discusses the chiral self-assembly of polymers in dispersion systems and its impact on polymer properties. By comparing traditional post-polymerization self-assembly and in situ PISA strategies, chirality control in polymers is predicted and advanced.
The chiral self-assembly of polymers in dispersions plays an important role in chiral chemistry and self-assembly. In general, both polymerization-induced self-assembly (PISA) and post-polymerization self-assembly can be used to prepare polymer nanoassemblies. In chirality induction or transfer processes, the self-assembly manner of the polymers greatly affects the chiral expression of the nanostructure and cannot be ignored in the chiral fields. Moreover, unique chiral expression and morphological transition of polymer assemblies in dispersions enable the preparation of advanced functional chiroptical materials. Herein, this Review discusses recent advances in chiral expression and morphology control in polymer dispersion systems, particularly the comparison between traditional post-polymerization self-assembly and in situ PISA strategies, to predict and advance chirality control in polymers.

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