Facile synthesis of hierarchically structured MIL-53(Al) with superior properties using an environmentally-friendly ultrasonic method for separating lead ions from aqueous solutions

The present study aims at investigating sonochemically synthesized MIL-53(Al) and its applications in adsorption lead ions from aqueous solution. XRD, FESEM, BET, and FTIR analyses were employed to identify and characterize MIL-53(Al). The ultrasonic-assisted synthesis procedure results in reducing the synthesis time to 24 h; however, the conventional synthesis of MIL-53(Al) takes 3 days. Applying ultrasonic waves also leads to increase of the specific surface area up to 50% more than that of synthesized by the conventional method, as well as creating the hierarchical MIL-53(Al) structure which reduces the mass transfer limitation of ions into internal micropores. The optimum conditions for removing lead ions are pH of 6, Pb+2 ion concentration of 20 mg/L, contact time of 60 min, adsorbent dose of 0.04 g, and temperature of 318 K with the removal efficiency of 97.63%. The experimental adsorption equilibrium and kinetic data fit the Langmuir isotherm and pseudo-second-order kinetic models, respectively. Moreover, the usage of sonochemically synthesized MIL-53(Al), for the first time as an adsorbent in heavy metal removal points to the great potential of this new environmentally-friendly adsorbent in removing lead ions from aqueous solutions

Automated summary

This study successfully synthesized MIL-53(Al) adsorbents through sonochemical-assisted synthesis and investigated their application in removing lead ions from aqueous solutions. The results showed that sonochemical-assisted synthesis could significantly reduce the synthesis time and increase the specific surface area of the adsorbents, thereby improving the mass transfer limitation in ion adsorption. The optimal conditions for lead ion removal were determined, and the applicability of adsorption equilibrium and kinetic models were verified. Furthermore, this study demonstrated the great potential of sonochemically synthesized MIL-53(Al) as an environmentally-friendly adsorbent for lead ion removal.