期刊
SCIENTIFIC REPORTS
卷 11, 期 1, 页码 -出版社
NATURE PORTFOLIO
DOI: 10.1038/s41598-021-98694-2
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资金
- Ministry of Education, Youth and Sports of the Czech Republic [RP/CPS/2020/006]
The study demonstrates that adding silicone oil to the Sylgard 184 system can soften the commercial silicone rubber, and the mechanical properties can be adjusted by curing temperature and silicone oil content, with the curing reaction exhibiting second-order kinetics.
Due to its simple curing and very good mechanical properties, Sylgard 184 belongs to the most widely and frequently used silicones in many industrial applications such as microfluidics and microengineering. On top of that its mechanical properties are further controllable through the curing temperature, which may vary from ambient temperature up to 200 degrees C; the lower the curing temperature the lower the mechanical properties (Johnston et al. in J Micromech Microeng 24:7, 2014. 10.1088/0960-1317/24/3/035017). However, certain specialised application may require even a softer binder than the low curing temperature allows for. In this study we show that this softening can be achieved with the addition of silicone oil into the Sylgard 184 system. To this end a series of Sylgard 184 samples with varying silicone oil concentrations were prepared and tested (tensile test, rotational rheometer) in order to determine how curing temperature and silicone oil content affect mechanical properties. Curing reaction of the polymer system was found to observe 2nd order kinetics in all cases, regardless the oil concentration used. The results suggest that within the tested concentration range the silicone oil addition can be used to soften commercial silicone Sylgard 184.
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