One-step fabrication of soft calcium superhydrophobic surfaces by a simple electrodeposition process

A simple, one-step electrodeposition process was rapidly performed on a metal substrate to fabricate calcium superhydrophobic surfaces in an electrolyte containing calcium chloride (CaCl2), myristic acid (CH3(CH2)(12)COOH), and ethanol, which can avoid the intricate post-processing of surface treatment. The morphology and surface chemical compositions of the fabricated superhydrophobic surfaces were systematically examined by means of SEM, XRD, and FTIR, respectively. The results indicate that the deposited surfaces were mainly composed of calcium myristate, which can dramatically lower surface free energy. The shortest process for constructing a superhydrophobic surface is about 0.5 min, and the maximum contact angle of the as-prepared surfaces can reach as high as 166 degrees, showing excellent superhydrophobicity. By adjusting the electrodeposition time, the structure of the cathodic surface transforms from the turfgrass structure, loose flower structures, larger and dense flower structures, secondary flower structures, and then into tertiary or more flower structures. The superhydrophobic surfaces showed excellent rebound performance with a high-speed camera. After a pressing force, their hardness increases, but the superhydrophobic performance is not weakened. Inversely, the bouncing performance is enhanced. This electrodeposition process offers a promising approach for large areas of superhydrophobic surfaces on conductive metals and strongly impacts the dynamics of water droplets.

Automated summary

This study presents a simple one-step electrodeposition process to fabricate superhydrophobic calcium surfaces on metal substrates in an electrolyte solution, avoiding complex post-treatment. The surfaces were mainly composed of calcium myristate, dramatically reducing surface free energy and achieving a maximum contact angle of 166 degrees. By adjusting the deposition time, the surface structure can be transformed, while the superhydrophobic surfaces exhibit excellent rebound performance and surface hardness after pressing force.