期刊
RSC ADVANCES
卷 12, 期 2, 页码 728-742出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1ra07013d
关键词
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资金
- National Natural Science Foundation of China [21878033]
- Talent Project of Liaoning University of Science and Technology [601011507-17]
The diamine monomer BHAPPP was synthesized and used to prepare a series of phthalide-containing PEIs, which exhibited superior gas separation performance. The TR membranes derived from these PEIs showed increased gas separation properties with higher thermal treatment temperatures.
The diamine monomer 3,3-bis[4-(3-hydroxy-4-amino-phenoxy)phenyl]phthalide (BHAPPP) was firstly synthesized by the nucleophilic substitution of 5-fluoro-2-nitrophenol and phenolphthalein, followed by a reduction reaction. A series of phthalide-containing poly(ether imide)s (PEI) were then prepared through the polycondensation of BHAPPP with six kinds of dianhydrides, including 4,4 '-(hexafluoroisopropylidene)diphthalic anhydride (6FDA), 3,3 ',4,4 '-benzophenone tetracarboxylic dianhydride (BTDA), 3,3 ',4,4 '-biphenyl tetracarboxylic dianhydride (BPDA), 4,4 '-oxydiphthalic dianhydride (ODPA), 1,2,3,4-cyclobutane tetracarboxylic dianhydride (CBDA) and pyromellitic dianhydride (PMDA), as well as thermal imidization. After further thermal treatment, the corresponding thermal rearrangement (TR) membranes were obtained. Due to the existence of the phthalide lactone ring, the PEIs probably underwent TR and crosslinking simultaneously. With the increase of thermal treatment temperature, the mechanical properties of the TR membranes dramatically decreased, but the gas separation properties obviously increased. When the PEIs were treated at 450 degrees C for 1 h, the CO2, H-2, O-2, N-2 and CH4 permeability of TR(BHAPPP-6FDA) reached 258.5, 190.5, 38.35, 4.25 and 2.15 Barrers, respectively. Meanwhile, the CO2/CH4 selectivity of 120.2 sharply exceeded the 2008 Robeson limit, and O-2/N-2 selectivity was 9.02, close to the 2015 upper limit. Therefore, the TR membranes derived from phthalide-containing PEIs exhibit superior gas separation performance, andare expected to be applied in the field of gas separation.
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