期刊
MATERIALS
卷 14, 期 23, 页码 -出版社
MDPI
DOI: 10.3390/ma14237115
关键词
X-ray photoelectron spectroscopy; clay intercalation; pillared clays; kaolinite; montmorillonite; hydrotalcite
类别
资金
- Australian Microscopy & Microanalysis Research Facility at Centre for Microscopy and Microanalysis, The University of Queensland
- University of the Philippines System
XPS analysis of layered clay systems with intercalated inorganic and organic compounds reveals valuable insights into the structure, coordination, and oxidative transformations of these compounds. By studying the shifts in binding energies and multiplet splitting, XPS can track changes in oxidation states and coordination environments within the materials.
Layered clay systems intercalated with inorganic and organic compounds were analyzed to highlight how XPS can provide information on the different environments surrounding a particular atom as well as provide discernments on the size, coordination, and structural and oxidative transformations of the intercalating/pillaring compounds. XPS data on the intercalation of urea and K-acetate in low- and high-defect kaolinite revealed the interaction of the intercalating group NH2 with the siloxane functional groups in the interlayer surface. The intercalation of HDTMA in Mt demonstrated the use of XPS in monitoring the change in conformation assumed by alkylammonium intercalating compounds in Mt with increasing CEC. Studies on the pillaring of Mt by Al-13 and Ga-13 by XPS allowed determination of the coordination of the pillaring compound within the Mt layer. Lastly, the intercalation of hexacyanoferrate in hydrotalcite demonstrated the capability of XPS in following changes in the oxidation state of the iron compound. These were gleaned from interpretation of the shifts in binding energies and presence of multiplet splitting in the XPS of the component elements of the minerals or the intercalating compounds.
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