4.8 Article

Highly Safe, Durable, Adaptable, and Flexible Fuel Cell Using Gel/Sponge Composite Material

期刊

ADVANCED ENERGY MATERIALS
卷 12, 期 6, 页码 -

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/aenm.202103178

关键词

agar gels; flexibility; fuel cells; safety; sponges

资金

  1. National Key R&D Program of China from the Ministry of Science and Technology of China [2020YFB1505700, 2016YFE0105700, 2016YFA0200700]
  2. National Natural Science Foundation of China [22172191]
  3. Dongyue Polymer Material Company of Dongyue Federation
  4. State Key Laboratory of Fluorinated Functional Membrane Materials (Dongyue Group institute)
  5. Dongyue Future Hydrogen Energy Materials Company
  6. Collaborative Innovation Center of Suzhou Nano Science and Technology

向作者/读者索取更多资源

By synthesizing a composite material consisting of agar gel and wood sponge, a highly safe, durable, and flexible air-breathing direct methanol fuel cell (DMFC) was developed. This gel/sponge composite showed high absorption rate, cyclic performance, methanol absorption capacity, energy content, and flexibility. The proposed DMFC demonstrated high safety, adaptability, flexibility, and energy density, proving the potential of absorbent materials in enhancing the performance of fuel cells.
With the rapid development of portable and wearable electronics, safety concerns over flexible energy devices are inevitable. Therefore, it is important to develop energy supplies that are safe for use. In this work, a highly safe, durable, adaptable, and flexible air-breathing direct methanol fuel cell (DMFC) is successfully prepared by synthesizing and applying a new composite material with agar gel and wood sponge, that is, a gel/sponge composite. The gel/sponge composite has a high absorption rate, high cyclic performance, high methanol absorption capacity, high energy content, and high flexibility. Moreover, the gel/sponge composite with 1.5% agar gel retains approximately 90% of the methanol solution at a pressure of 29.4 kPa, and the areal energy density of the proposed DMFC approaches 13.7 mWh cm(-2). Both the single-cell and stack of DMFC with the new composite material successfully survive a series of destructive tests, including needle penetration, cutting, and compression. Therefore, it is successfully demonstrated that absorbent materials can greatly boost the safety, adaptability, flexibility, and energy density of air-breathing DMFCs. Furthermore, this concept shows promise in improving the safety of other fuel cells by using absorbent materials to solidify their gaseous or liquid fuels.

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