4.8 Review

Dual-Metal Atom Electrocatalysts: Theory, Synthesis, Characterization, and Applications

相关参考文献

注意:仅列出部分参考文献,下载原文获取全部文献信息。
Review Chemistry, Multidisciplinary

In Situ/Operando Electrocatalyst Characterization by X-ray Absorption Spectroscopy

Janis Timoshenko et al.

Summary: X-ray absorption spectroscopy (XAS) is a crucial method for investigating the structure and composition of heterogeneous catalysts, revealing the nature of active sites and establishing links between structural motifs, local electronic structure, and catalytic properties. Recent advancements in instrumentation and data analysis approaches for deciphering X-ray absorption near edge structure (XANES) and extended X-ray absorption fine structure (EXAFS) spectra have been discussed, with emphasis on applications in the field of heterogeneous catalysis, particularly in electrocatalysis.

CHEMICAL REVIEWS (2021)

Review Energy & Fuels

Recent Progress of Sn-Based Derivative Catalysts for Electrochemical Reduction of CO2

Feng Cheng et al.

Summary: This paper discusses the importance of using renewable electric power to drive CO2 electrochemical reduction for producing high-value-added chemical fuels and summarizes the application and development of tin-based catalysts in CO2RR research. The study points out that tin-based catalysts may be widely used due to their low cost, environmental friendliness, and high selectivity towards formic acid, showing great potential for practical applications.

ENERGY TECHNOLOGY (2021)

Review Chemistry, Multidisciplinary

More is Different: Synergistic Effect and Structural Engineering in Double-Atom Catalysts

Yiran Ying et al.

Summary: Double-atom catalysts (DACs) have emerged as a novel frontier in heterogeneous catalysis, showing improved catalytic activity through synergistic effects while maintaining high atomic utilization efficiency, good selectivity, and stability. Current research focuses on the design, experimental and theoretical progress, and practical applications of DACs in various catalytic reactions.

ADVANCED FUNCTIONAL MATERIALS (2021)

Article Electrochemistry

Tracking oxygen atoms in electrochemical CO oxidation - Part II: Lattice oxygen reactivity in oxides of Pt and Ir

Soren B. Scott et al.

Summary: Through chip-based electrochemistry mass spectrometry with isotope labeling, we revealed the involvement of lattice oxygen in the electrochemical oxidation of carbon monoxide on Pt and Ir electrocatalysts. In Pt, *OH is the reactive species for CO oxidation, while in Ir only lattice oxygen activated by a reductive sweep participates in the reaction.

ELECTROCHIMICA ACTA (2021)

Article Chemistry, Physical

A comparison of single and double Co sites incorporated in N-doped graphene for the oxygen reduction reaction

Katrine L. Svane et al.

Summary: Metal and nitrogen co-doped carbons (M-N/Cs) show promising potential as alternatives to platinum-based catalysts for the oxygen reduction reaction (ORR). Density functional theory calculations were used to compare the ORR activity of Co single and double sites embedded in N-doped carbon, revealing significant deviations in the scaling relations for the double site in the graphene sheet. The effects of different implicit and explicit solvent models on the adsorption energies of ORR intermediates were also investigated, highlighting the influence of explicit water molecules on the stability and coordination of the catalyst.

JOURNAL OF CATALYSIS (2021)

Article Biochemical Research Methods

A sensitivity leap for X-band EPR using a probehead with a cryogenic preamplifier

Mantas Simenas et al.

Summary: This study presents an upgraded X-band EPR probehead equipped with a cryogenic low-noise preamplifier, showcasing significant enhancements in sensitivity and signal-to-noise ratio. By suppressing room temperature noise and sacrificing microwave power, the signal-to-noise ratio improvement can reach up to 15, resulting in a remarkable 200-fold reduction in EPR measurement time at 6K temperature.

JOURNAL OF MAGNETIC RESONANCE (2021)

Article Chemistry, Multidisciplinary

Tuning the Reactivity of Cofacial Porphyrin Prisms for Oxygen Reduction Using Modular Building Blocks

Matthew R. Crawley et al.

Summary: This study focused on assembling eight cofacial porphyrin prisms using MTPyP and functionalized ruthenium-based molecular clips, demonstrating significant improvement in catalytic rate constant k(s) and selectivity for the 4e(-)/4H* reduction of O-2 to H2O. The role of steric bulk of the clip in the structural dynamics of these prisms, which modulates the ORR reactivity with respect to selectivity and kinetics, was highlighted.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

Article Multidisciplinary Sciences

Unraveling CO adsorption on model single-atom catalysts

Jan Hulva et al.

Summary: The study reveals that the adsorption strength of CO on single metal sites differs from that on metal surfaces and supported clusters, as charge transfer affects the d-states of the metal atom and the metal-CO bond strength. CO-induced structural distortions reduce adsorption energies, with the extent of relaxations depending on local geometry.

SCIENCE (2021)

Article Chemistry, Physical

Three-Dimensional Carbon Electrocatalysts for CO2 or CO Reduction

Hao Wan et al.

Summary: This study investigates 3D carbon electrocatalysts as potential CO2RR electrocatalysts through density functional theory simulations and proposes a molecular-level engineering strategy. Results show that the introduction of a second metal center in diporphyrin molecules can produce CH4 and C-2 species, while coordination catalysts with pyridine can generate CH3OH and enable C-C coupling to form C-2 species.

ACS CATALYSIS (2021)

Article Chemistry, Multidisciplinary

Potential-Induced Spin Changes in Fe/N/C Electrocatalysts Assessed by In Situ X-ray Emission Spectroscopy

Viktoriia A. Saveleva et al.

Summary: This study investigates the electronic structure of molecular sites in two Fe/N/C catalysts by probing their average spin state using X-ray emission spectroscopy (XES), revealing for the first time the existence of reversible, potential-induced spin state changes in these materials.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Article Chemistry, Physical

Online Electrochemistry-Mass Spectrometry Evaluation of the Acidic Oxygen Evolution Reaction at Supported Catalysts

Junheng Huang et al.

Summary: The study utilizes a chip EC-MS system to investigate a graphene-supported ruthenium catalyst with high OER activity, enabling accurate measurement of onset potential and Faradaic efficiency while decoupling complex electrochemical reactions. Different stages of the OER process and side reactions are also studied using this technique.

ACS CATALYSIS (2021)

Review Chemistry, Physical

Status and challenges for the application of platinum group metal-free catalysts in proton-exchange membrane fuel cells

Luigi Osmieri et al.

Summary: Significant progress has been made in the development of platinum group metal-free electrocatalysts over the past decade, focusing on synthesis strategies for controlled active site formation and performance gains through electrode engineering. There is also a growing emphasis on durability, understanding degradation mechanisms, and the need for standard performance and accelerated stress test protocols.

CURRENT OPINION IN ELECTROCHEMISTRY (2021)

Article Chemistry, Multidisciplinary

Highly Selective CO2 Electroreduction to C2H4 Using a Metal-Organic Framework with Dual Active Sites

Xiao-Feng Qiu et al.

Summary: In this study, a metal-organic framework (PcCu-Cu-O) was reported as an electrocatalyst for converting CO2 to C2H4, showing higher efficiency compared to discrete molecular copper-phthalocyanine. In-situ infrared spectroscopy and control experiments indicated that the synergistic effect between the CuPc unit and the CuO4 unit contributes to lowering the energy barrier for C-C dimerization.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

Article Chemistry, Physical

Proton-filtering covalent organic frameworks with superior nitrogen penetration flux promote ambient ammonia synthesis

Sisi Liu et al.

Summary: By controlling the diffusion of reactants and using proton-filtering covalent organic frameworks, a highly selective and active nitrogen reduction was achieved in electrochemical ammonia synthesis. This strategy optimizes mass transfer and provides guidelines for practical green ammonia production.

NATURE CATALYSIS (2021)

Article Chemistry, Multidisciplinary

Iron, Nitrogen Co-Doped Carbon Spheres as Low Cost, Scalable Electrocatalysts for the Oxygen Reduction Reaction

Jingyu Feng et al.

Summary: Atomically dispersed transition metal-nitrogen-carbon catalysts are emerging as low-cost electrocatalysts for the oxygen reduction reaction in fuel cells. A synthesis strategy for these catalysts is still required, as well as a greater understanding of their mechanisms. Iron, nitrogen co-doped carbon spheres (Fe@NCS) have been prepared and FeN4 is identified as the main form of iron existing in the obtained Fe@NCS. Starting from Fe2+ and Fe3+ precursors, catalysts show chemical and structural differences. Fe2+@NCS-A displays better catalytic activity for the oxygen reduction reaction and shows potential for developing high-performance, low-cost fuel cell catalysts.

ADVANCED FUNCTIONAL MATERIALS (2021)

Article Chemistry, Physical

Tailored Brownmillerite Oxide Catalyst with Multiple Electronic Functionalities Enables Ultrafast Water Oxidation

Yinlong Zhu et al.

Summary: The research demonstrates that the A/B-site cosubstitution strategy can optimize the electronic structures of oxygen-deficient brownmillerite oxides to enhance OER catalytic performance. The optimized CaSrCoFeO6-delta (CSCF) exhibits multiple advantageous electronic structure features for OER catalysis, achieving ultrahigh activity outperforming noble metals and other metal oxides.

CHEMISTRY OF MATERIALS (2021)

Article Electrochemistry

In-situ detection of active sites for carbon-based bifunctional oxygen reduction and evolution catalysis

Richard W. Haid et al.

Summary: Carbon-based electrodes are increasingly popular as electrocatalysts for fuel cells and metal-air batteries due to their availability and versatility. This study investigated the surface behavior of highly oriented pyrolytic graphite under both ORR and OER conditions in 0.1 M KOH. By using noise analysis in electrochemical scanning tunneling microscopy, active sites were monitored and compared with nanoscale resolution. The results showed that step sites and defects are active for both ORR and OER, while terraces sites are largely inactive and only become involved in the OER at higher potentials. Surface degradation was evaluated during the operation, with no clear evidence of surface destruction observed in the experiments.

ELECTROCHIMICA ACTA (2021)

Article Physics, Condensed Matter

A novel fuel cell design for operando energy-dispersive x-ray absorption measurements

A. S. Leach et al.

Summary: A polymer electrolyte fuel cell has been designed for operando x-ray absorption spectroscopy (XAS) measurements of catalysts under standard fuel cell conditions, providing quality XAS data. Results from the cell operation showed good performance as a fuel cell and allowed time-resolved spectral measurements of catalysts in a fully-operating fuel cell.

JOURNAL OF PHYSICS-CONDENSED MATTER (2021)

Article Chemistry, Multidisciplinary

Atomically Precise Dinuclear Site Active toward Electrocatalytic CO2 Reduction

Tao Ding et al.

Summary: The study reports a novel strategy to develop atomically precise Ni-2 sites and demonstrates their efficient catalytic performance in the electrochemical CO2 reduction reaction. The key O-Ni-2-N-6 structure significantly lowers the energy barrier for CO2 activation, leading to enhanced CO production with >94% Faradaic efficiency. The findings provide insights into the synergy mechanism of dinuclear catalysts and offer a bottom-up synthesis approach for efficient catalytic reactions.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

Article Chemistry, Physical

Chemical vapour deposition of Fe-N-C oxygen reduction catalysts with full utilization of dense Fe-N4 sites

Li Jiao et al.

Summary: Replacing scarce and expensive platinum with metal-nitrogen-carbon (M-N-C) catalysts for the oxygen reduction reaction in proton exchange membrane fuel cells has been impeded by the low active site density and site utilization of M-N-C. These limitations have now been overcome by implementing trans-metalation of Zn-N-4 sites into Fe-N-4 sites.

NATURE MATERIALS (2021)

Editorial Material Multidisciplinary Sciences

Is lithium the key for nitrogen electroreduction?

Olivia Westhead et al.

SCIENCE (2021)

Article Multidisciplinary Sciences

Nitrogen reduction to ammonia at high efficiency and rates based on a phosphonium proton shuttle

Bryan H. R. Suryanto et al.

Summary: Ammonia (NH3) is a globally important commodity for fertilizer production, but its synthesis by the Haber-Bosch process causes substantial emissions of carbon dioxide. Alternative methods being explored include the promising electrochemical lithium-mediated nitrogen reduction reaction, which has required sacrificial sources of protons. In this study, a phosphonium salt is introduced as a proton shuttle to help resolve this limitation, resulting in high NH3 production rates and demonstrated continuous operation for more than 3 days.

SCIENCE (2021)

Article Chemistry, Physical

Role of Catalyst in Controlling N2 Reduction Selectivity: A Unified View of Nitrogenase and Solid Electrodes

Alexander Bagger et al.

Summary: The study explores the catalyst space for N-2 reduction reaction under different conditions, revealing the challenge of achieving selective N-2 reduction without producing H-2 under standard conditions.

ACS CATALYSIS (2021)

Article Multidisciplinary Sciences

Methods for nitrogen activation by reduction and oxidation

Haldrian Iriawan et al.

Summary: The article introduces the importance of the industrial Haber-Bosch process for producing ammonia in modern society, discusses the challenges of N-2 activation and the drawbacks of the Haber-Bosch process, proposes new strategies for sustainable N-2 activation, compares the latest research results from different catalytic reactions, and discusses best practices for improving reproducibility and cost-effective methods for rigorous experimentation.

NATURE REVIEWS METHODS PRIMERS (2021)

Article Multidisciplinary Sciences

Atom probe tomography

Baptiste Gault et al.

Summary: APT provides three-dimensional compositional mapping with sub-nanometre resolution and high sensitivity for all elements. The overview covers the development, specimen preparation, data reconstruction, analysis, applications, performance underpinning, strengths, limitations, and potential improvements of APT. Future advancements aim for true atomic-scale tomography through new specimen preparation methods, novel technologies, and interoperability with complementary techniques.

NATURE REVIEWS METHODS PRIMERS (2021)

Review Multidisciplinary Sciences

In situ electron paramagnetic resonance spectroscopy for catalysis

Shannon A. Bonke et al.

Summary: In situ catalysis studies using electron paramagnetic resonance provide insight into species under reaction conditions, helping to elucidate reaction mechanisms and optimize catalyst reactivity. This method is applicable in various areas such as high-temperature gas-solid reactions, molecular catalysis, photocatalysis, and electrocatalysis, with a focus on unraveling catalytic mechanisms.

NATURE REVIEWS METHODS PRIMERS (2021)

Article Green & Sustainable Science & Technology

Active Site Identification in FeNC Catalysts and Their Assignment to the Oxygen Reduction Reaction Pathway by In Situ Fe-57 Mossbauer Spectroscopy

Lingmei Ni et al.

Summary: This study identified the active site species in different FeNC catalysts prepared through various routes, revealing common spectral changes during the direct electroreduction of oxygen. However, changes in selectivity were attributed to variations within additional species. Density functional theory calculations provided insights into the nature of nitrogen coordination in FeN4 moieties involved in the oxygen reduction reaction.

ADVANCED ENERGY AND SUSTAINABILITY RESEARCH (2021)

Review Chemistry, Physical

Oxygen Reduction Reactions on Single- or Few-Atom Discrete Active Sites for Heterogeneous Catalysis

Tiva Sharifi et al.

ADVANCED ENERGY MATERIALS (2020)

Review Chemistry, Physical

3D Carbon Materials for Efficient Oxygen and Hydrogen Electrocatalysis

Ana Belen Jorge et al.

ADVANCED ENERGY MATERIALS (2020)

Review Chemistry, Multidisciplinary

Electron Transfer in Nitrogenase

Hannah L. Rutledge et al.

CHEMICAL REVIEWS (2020)

Review Chemistry, Physical

Heterogeneous Single Atom Electrocatalysis, Where Singles Are Married

Wenjie Zang et al.

ADVANCED ENERGY MATERIALS (2020)

Review Chemistry, Multidisciplinary

Single Atom on the 2D Matrix: An Emerging Electrocatalyst for Energy Applications

Bishnupad Mohanty et al.

ACS OMEGA (2020)

Article Chemistry, Multidisciplinary

Enhanced CO2 Electroreduction on Neighboring Zn/Co Monomers by Electronic Effect

Wenjin Zhu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Article Chemistry, Multidisciplinary

Bridge Bonded Oxygen Ligands between Approximated FeN(4)Sites Confer Catalysts with High ORR Performance

Liyuan Gong et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Article Multidisciplinary Sciences

Selective electroreduction of CO2 to acetone by single copper atoms anchored on N-doped porous carbon

Kun Zhao et al.

NATURE COMMUNICATIONS (2020)

Article Materials Science, Multidisciplinary

Supported and coordinated single metal site electrocatalysts

Qiurong Shi et al.

MATERIALS TODAY (2020)

Article Chemistry, Physical

In Situ/Operando Studies for Designing Next-Generation Electrocatalysts

Yanping Zhu et al.

ACS ENERGY LETTERS (2020)

Article Chemistry, Physical

Dual-atom Ag2/graphene catalyst for efficient electroreduction of CO2 to CO

Yifan Li et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2020)

Article Multidisciplinary Sciences

O-coordinated W-Mo dual-atom catalyst for pH-universal electrocatalytic hydrogen evolution

Yang Yang et al.

SCIENCE ADVANCES (2020)

Article Nanoscience & Nanotechnology

Comparative Study of PtNi Nanowire Array Electrodes toward Oxygen Reduction Reaction by Half-Cell Measurement and PEMFC Test

Peter Mardle et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

Article Chemistry, Multidisciplinary

Chemical Vapor Deposition for Atomically Dispersed and Nitrogen Coordinated Single Metal Site Catalysts

Shengwen Liu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Article Materials Science, Multidisciplinary

Atomic-Scale Structural Mapping of Active Sites in Monolayer PGM-Free Catalysts by Low-Voltage 4D-STEM

Michael Zachman et al.

MICROSCOPY AND MICROANALYSIS (2020)

Article Materials Science, Multidisciplinary

Retaining Precision at Low-Dose and High-Speed STEM Imaging Conditions

Tiarnan Mullarkey et al.

MICROSCOPY AND MICROANALYSIS (2020)

Review Chemistry, Multidisciplinary

Fundamentals, Applications, and Future Directions of Bioelectrocatalysis

Hui Chen et al.

CHEMICAL REVIEWS (2020)

Article Chemistry, Physical

Resonance-Promoted Formic Acid Oxidation via Dynamic Electrocatalytic Modulation

Joshua Gopeesingh et al.

ACS CATALYSIS (2020)

Review Chemistry, Physical

Electrocatalysis of Single-Atom Sites: Impacts of Atomic Coordination

Bingzhang Lu et al.

ACS CATALYSIS (2020)

Article Chemistry, Physical

Supported Metal Pair-Site Catalysts

Erjia Guan et al.

ACS CATALYSIS (2020)

Review Multidisciplinary Sciences

Using nature's blueprint to expand catalysis with Earth-abundant metals

R. Morris Bullock et al.

SCIENCE (2020)

Editorial Material Multidisciplinary Sciences

Single atom catalysis: a decade of stunning progress and the promise for a bright future

Sharon Mitchell et al.

NATURE COMMUNICATIONS (2020)

Article Chemistry, Physical

Circumventing Scaling Relations in Oxygen Electrochemistry Using Metal-Organic Frameworks

Tyler Sours et al.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2020)

Article Multidisciplinary Sciences

Identification and elimination of false positives in electrochemical nitrogen reduction studies

Jaecheol Choi et al.

NATURE COMMUNICATIONS (2020)

Review Chemistry, Multidisciplinary

C2N: A Class of Covalent Frameworks with Unique Properties

Zhihong Tian et al.

ADVANCED SCIENCE (2020)

Review Chemistry, Multidisciplinary

Metal oxide-based materials as an emerging family of hydrogen evolution electrocatalysts

Yinlong Zhu et al.

ENERGY & ENVIRONMENTAL SCIENCE (2020)

Review Chemistry, Multidisciplinary

Operando characterization techniques for electrocatalysis

Jingkun Li et al.

ENERGY & ENVIRONMENTAL SCIENCE (2020)

Article Chemistry, Multidisciplinary

Increasing stability, efficiency, and fundamental understanding of lithium-mediated electrochemical nitrogen reduction

Suzanne Z. Andersen et al.

ENERGY & ENVIRONMENTAL SCIENCE (2020)

Review Chemistry, Physical

Polymeric carbon nitrides and related metal-free materials for energy and environmental applications

Jesus Barrio et al.

JOURNAL OF MATERIALS CHEMISTRY A (2020)

Article Chemistry, Multidisciplinary

A highly efficient diatomic nickel electrocatalyst for CO2reduction

Meng-Jiao Sun et al.

CHEMICAL COMMUNICATIONS (2020)

Review Chemistry, Applied

Supported dual-atom catalysts: Preparation, characterization, and potential applications

Jing Zhang et al.

CHINESE JOURNAL OF CATALYSIS (2020)

Article Chemistry, Multidisciplinary

Establishing reactivity descriptors for platinum group metal (PGM)-free Fe-N-C catalysts for PEM fuel cells

Mathias Primbs et al.

ENERGY & ENVIRONMENTAL SCIENCE (2020)

Review Chemistry, Multidisciplinary

Atomic site electrocatalysts for water splitting, oxygen reduction and selective oxidation

Di Zhao et al.

CHEMICAL SOCIETY REVIEWS (2020)

Review Chemistry, Physical

Single-atom catalysts for electrochemical clean energy conversion: recent progress and perspectives

Huining Li et al.

SUSTAINABLE ENERGY & FUELS (2020)

Article Chemistry, Multidisciplinary

Structure Sensitivity in the Electrocatalytic Reduction of CO2 with Gold Catalysts

Stefano Mezzavilla et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

Article Chemistry, Multidisciplinary

Ultrahigh-Loading Zinc Single-Atom Catalyst for Highly Efficient Oxygen Reduction in Both Acidic and Alkaline Media

Jia Li et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

Article Chemistry, Multidisciplinary

Isolated Diatomic Ni-Fe Metal-Nitrogen Sites for Synergistic Electroreduction of CO2

Wenhao Ren et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

Article Chemistry, Multidisciplinary

Atom-by-Atom Resolution of Structure-Function Relations over Low-Nuclearity Metal Catalysts

Evgeniya Vorobyeva et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

Article Chemistry, Multidisciplinary

Charge Polarization from Atomic Metals on Adjacent Graphitic Layers for Enhancing the Hydrogen Evolution Reaction

Longzhou Zhang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

Article Multidisciplinary Sciences

A rigorous electrochemical ammonia synthesis protocol with quantitative isotope measurements

Suzanne Z. Andersen et al.

NATURE (2019)

Article Chemistry, Multidisciplinary

Elucidating the Structural Composition of a Fe-N-C Catalyst by Nuclear- and Electron-Resonance Techniques

Stephan Wagner et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

Article Chemistry, Multidisciplinary

Local Structure and Coordination Define Adsorption in a Model Ir1/Fe3O4 Single-Atom Catalyst

Zdenek Jakub et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

Article Electrochemistry

The degradation of Pt/IrOx oxygen bifunctional catalysts

Gabriel C. da Silva et al.

ELECTROCHIMICA ACTA (2019)

Article Chemistry, Multidisciplinary

Bacterial Respiratory Chain Diversity Reveals a Cytochrome c Oxidase Reducing O2 at Low Overpotentials

Xie Wang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

Review Chemistry, Applied

Perspectives on Low-Temperature Electrolysis and Potential for Renewable Hydrogen at Scale

Katherine Ayers et al.

ANNUAL REVIEW OF CHEMICAL AND BIOMOLECULAR ENGINEERING, VOL 10 (2019)

Article Chemistry, Physical

Strategies toward Selective Electrochemical Ammonia Synthesis

Aayush R. Singh et al.

ACS CATALYSIS (2019)

Article Chemistry, Physical

Electrochemical Reduction of CO2 on Metal-Nitrogen-Doped Carbon Catalysts

Ana Sofia Varela et al.

ACS CATALYSIS (2019)

Editorial Material Chemistry, Physical

Platinum group metal-free catalysts boost cost competitiveness of fuel cell vehicles

Simon T. Thompson et al.

NATURE CATALYSIS (2019)

Article Chemistry, Multidisciplinary

A Cobalt-Iron Double-Atom Catalyst for the Oxygen Evolution Reaction

Lichen Bai et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

Article Multidisciplinary Sciences

Atomically precise, custom-design origami graphene nanostructures

Hui Chen et al.

SCIENCE (2019)

Article Multidisciplinary Sciences

Rational synthesis of an atomically precise carboncone under mild conditions

Zheng-Zhong Zhu et al.

SCIENCE ADVANCES (2019)

Article Chemistry, Inorganic & Nuclear

Examination of the Magneto-Structural Effects of Hangman Groups on Ferric Porphyrins by EPR

Joscha Nehrkorn et al.

INORGANIC CHEMISTRY (2019)

Article Chemistry, Multidisciplinary

Climbing the Apex of the ORR Volcano Plot via Binuclear Site Construction: Electronic and Geometric Engineering

Meiling Xiao et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

Article Chemistry, Multidisciplinary

A Long π-Conjugated Poly(para-Phenylene)-Based Polymeric Segment of Single-Walled Carbon Nanotubes

Qiang Huang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

Article Multidisciplinary Sciences

Highly selective oxygen reduction to hydrogen peroxide on transition metal single atom coordination

Kun Jiang et al.

NATURE COMMUNICATIONS (2019)

Article Chemistry, Multidisciplinary

An Isolated Zinc-Cobalt Atomic Pair for Highly Active and Durable Oxygen Reduction

Ziyang Lu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

Article Chemistry, Physical

Strategies to break linear scaling relationships

Javier Perez-Ramirez et al.

NATURE CATALYSIS (2019)

Article Multidisciplinary Sciences

pH effects on the electrochemical reduction of CO(2) towards C2 products on stepped copper

Xinyan Liu et al.

NATURE COMMUNICATIONS (2019)

Article Chemistry, Multidisciplinary

Climbing the 3D Volcano for the Oxygen Reduction Reaction Using Porphyrin Motifs

Hao Wan et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2019)

Article Chemistry, Physical

Partially Dissociated Water Dimers at the Water-Hematite Interface

Zdenek Jakub et al.

ACS ENERGY LETTERS (2019)

Article Chemistry, Physical

Electrifying the Haber–Bosch

Marcal Capdevila-Cortada

Nature Catalysis (2019)

Review Chemistry, Physical

Atomic (single, double, and triple atoms) catalysis: frontiers, opportunities, and challenges

Z. W. Chen et al.

JOURNAL OF MATERIALS CHEMISTRY A (2019)

Article Chemistry, Multidisciplinary

The first atomic layer deposition process for FexN films

Liyong Du et al.

CHEMICAL COMMUNICATIONS (2019)

Review Chemistry, Multidisciplinary

Single atom electrocatalysts supported on graphene or graphene-like carbons

Huilong Fei et al.

CHEMICAL SOCIETY REVIEWS (2019)

Article Chemistry, Multidisciplinary

Synergetic interaction between neighboring platinum and ruthenium monomers boosts CO oxidation

Peng Zhou et al.

CHEMICAL SCIENCE (2019)

Review Materials Science, Multidisciplinary

Review-On Atomic Layer Deposition: Current Progress and Future Challenges

Bikash Chandra Mallick et al.

ECS JOURNAL OF SOLID STATE SCIENCE AND TECHNOLOGY (2019)

Review Chemistry, Physical

Recent Advances for MOF-Derived Carbon-Supported Single-Atom Catalysts

Aijuan Han et al.

SMALL METHODS (2019)

Article Chemistry, Physical

Understanding Continuous Lithium-Mediated Electrochemical Nitrogen Reduction

Nikifar Lazouski et al.

Review Chemistry, Physical

Electrochemical Scanning Probe Microscopies in Electrocatalysis

Yunchang Hang et al.

SMALL METHODS (2019)

Review Materials Science, Multidisciplinary

Strategies to Break the Scaling Relation toward Enhanced Oxygen Electrocatalysis

Zhen-Feng Huang et al.

MATTER (2019)

Article Chemistry, Multidisciplinary

Elucidation of the Oxygen Reduction Volcano in Alkaline Media using a Copper-Platinum(111) Alloy

Kim D. Jensen et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

Review Chemistry, Multidisciplinary

Understanding Catalytic Activity Trends in the Oxygen Reduction Reaction

Ambarish Kulkarni et al.

CHEMICAL REVIEWS (2018)

Review Chemistry, Multidisciplinary

Oxygen Activation and Energy Conservation by Cytochrome c Oxidase

Marten Wikstrom et al.

CHEMICAL REVIEWS (2018)

Review Chemistry, Multidisciplinary

Principles and applications of EPR spectroscopy in the chemical sciences

Maxie M. Roessler et al.

CHEMICAL SOCIETY REVIEWS (2018)

Article Engineering, Environmental

Mapping Global Flows of Chemicals: From Fossil Fuel Feedstocks to Chemical Products

Peter G. Levi et al.

ENVIRONMENTAL SCIENCE & TECHNOLOGY (2018)

Article Chemistry, Multidisciplinary

Single-Atom Au/NiFe Layered Double Hydroxide Electrocatalyst: Probing the Origin of Activity for Oxygen Evolution Reaction

Jingfang Zhang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

Article Electrochemistry

Analysis of Voltage Losses in PEM Water Electrolyzers with Low Platinum Group Metal Loadings

Maximilian Bernt et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2018)

Article Multidisciplinary Sciences

Carbon nitride supported Fe2 cluster catalysts with superior performance for alkene epoxidation

Shubo Tian et al.

NATURE COMMUNICATIONS (2018)

Article Chemistry, Physical

Toward the Decentralized Electrochemical Production of H2O2: A Focus on the Catalysis

Sungeun Yang et al.

ACS CATALYSIS (2018)

Article Chemistry, Physical

Toward Platinum Group Metal-Free Catalysts for Hydrogen/AirProton-Exchange Membrane Fuel Cells

Frederic Jaouen et al.

JOHNSON MATTHEY TECHNOLOGY REVIEW (2018)

Article Chemistry, Multidisciplinary

Coordination of Atomic Co-Pt Coupling Species at Carbon Defects as Active Sites for Oxygen Reduction Reaction

Longzhou Zhang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

Article Chemistry, Physical

Double-atom catalysts: transition metal dimer-anchored C2N monolayers as N2 fixation electrocatalysts

Xu Zhang et al.

JOURNAL OF MATERIALS CHEMISTRY A (2018)

Article Chemistry, Multidisciplinary

End-On Bound Iridium Dinuclear Heterogeneous Catalysts on WO3 for Solar Water Oxidation

Yanyan Zhao et al.

ACS CENTRAL SCIENCE (2018)

Article Chemistry, Multidisciplinary

Fabrication of Single-Atom Catalysts with Precise Structure and High Metal Loading

Jing Wang et al.

ADVANCED MATERIALS (2018)

Article Chemistry, Physical

CO2 Electroreduction Performance of Phthalocyanine Sheet with Mn Dimer: A Theoretical Study

Haoming Shen et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2017)

Article Chemistry, Multidisciplinary

Design of N-Coordinated Dual-Metal Sites: A Stable and Active Pt-Free Catalyst for Acidic Oxygen Reduction Reaction

Jing Wang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

Review Multidisciplinary Sciences

Combining theory and experiment in electrocatalysis: Insights into materials design

Zhi Wei Seh et al.

SCIENCE (2017)

Article Multidisciplinary Sciences

Bottom-up precise synthesis of stable platinum dimers on graphene

Huan Yan et al.

NATURE COMMUNICATIONS (2017)

Article Energy & Fuels

Sustainion Imidazolium-Functionalized Polymers for Carbon Dioxide Electrolysis

Robert B. Kutz et al.

ENERGY TECHNOLOGY (2017)

Article Chemistry, Physical

Electrochemical CO2 Reduction: A Classification Problem

Alexander Bagger et al.

CHEMPHYSCHEM (2017)

Article Chemistry, Multidisciplinary

Potential-Cycling Synthesis of Single Platinum Atoms for Efficient Hydrogen Evolution in Neutral Media

Lihan Zhang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)

Review Chemistry, Multidisciplinary

Perspectives on metal-organic frameworks with intrinsic electrocatalytic activity

Marcello B. Solomon et al.

CRYSTENGCOMM (2017)

Review Chemistry, Multidisciplinary

Reactivity Descriptors for the Activity of Molecular MN4 Catalysts for the Oxygen Reduction Reaction

Jose H. Zagal et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)

Article Chemistry, Multidisciplinary

Exploiting redox activity in metal-organic frameworks: concepts, trends and perspectives

D. M. D'Alessandro

CHEMICAL COMMUNICATIONS (2016)

Article Biochemistry & Molecular Biology

Silver(I) complexes with phthalazine and quinazoline as effective agents against pathogenic Pseudomonas aeruginosa strains

Biljana D. Glisic et al.

JOURNAL OF INORGANIC BIOCHEMISTRY (2016)

Article Chemistry, Physical

Design of Efficient Catalysts with Double Transition Metal Atoms on C2N Layer

Xiyu Li et al.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2016)

Article Chemistry, Multidisciplinary

On an Easy Way To Prepare Metal Nitrogen Doped Carbon with Exclusive Presence of MeN4-type Sites Active for the ORR

Ulrike I. Kramm et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)

News Item Chemistry, Multidisciplinary

CARBON MATERIALS MOF morphologies in control

Jing Tang et al.

NATURE CHEMISTRY (2016)

Editorial Material Multidisciplinary Sciences

Toward sustainable fuel cells

Ifan Erfyl Lester Stephens et al.

SCIENCE (2016)

Article Multidisciplinary Sciences

In situ electrochemical quantification of active sites in Fe-N/C non-precious metal catalysts

Daniel Malko et al.

NATURE COMMUNICATIONS (2016)

Review Nanoscience & Nanotechnology

Mesoporous materials for energy conversion and storage devices

Wei Li et al.

NATURE REVIEWS MATERIALS (2016)

Review Chemistry, Multidisciplinary

On the Role of Metals in Nitrogen-Doped Carbon Electrocatalysts for Oxygen Reduction

Justus Masa et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2015)

Article Chemistry, Multidisciplinary

Iron Carbide Nanoparticles Encapsulated in Mesoporous Fe-N-Doped Carbon Nanofibers for Efficient Electrocatalysis

Zhen-Yu Wu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2015)

Article Multidisciplinary Sciences

Nitrogenated holey two-dimensional structures

Javeed Mahmood et al.

NATURE COMMUNICATIONS (2015)

Article Multidisciplinary Sciences

Quantifying the density and utilization of active sites in non-precious metal oxygen electroreduction catalysts

Nastaran Ranjbar Sahraie et al.

NATURE COMMUNICATIONS (2015)

Article Multidisciplinary Sciences

Catalysis on singly dispersed bimetallic sites

Shiran Zhang et al.

NATURE COMMUNICATIONS (2015)

Article Chemistry, Physical

Water as a Promoter and Catalyst for Dioxygen Electrochemistry in Aqueous and Organic Media

Jakub Staszak-Jirkovsky et al.

ACS CATALYSIS (2015)

Article Chemistry, Physical

Structure of Fe-Nx-C Defects in Oxygen Reduction Reaction Catalysts from First-Principles Modeling

Edward F. Holby et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2014)

Article Chemistry, Multidisciplinary

Atomic Structure and Dynamics of Metal Dopant Pairs in Graphene

Zhengyu He et al.

NANO LETTERS (2014)

Article Chemistry, Physical

Elucidating the activity of stepped Pt single crystals for oxygen reduction

Aliaksandr S. Bandarenka et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2014)

Article Chemistry, Physical

Beyond the volcano limitations in electrocatalysis - oxygen evolution reaction

Niels Bendtsen Halck et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2014)

Article Chemistry, Physical

Catalyzing the Hydrogen Evolution Reaction (HER) with Molybdenum Sulfide Nanomaterials

Jesse D. Benck et al.

ACS CATALYSIS (2014)

Review Biochemistry & Molecular Biology

Nitrogenase reduction of carbon-containing compounds

Lance C. Seefeldt et al.

BIOCHIMICA ET BIOPHYSICA ACTA-BIOENERGETICS (2013)

Article Chemistry, Inorganic & Nuclear

Synthesis, characterization, OFET and electrochemical properties of novel dimeric metallophthalocyanines

Lale Meyanci Ozer et al.

DALTON TRANSACTIONS (2013)

Article Chemistry, Physical

Understanding Trends in the Electrocatalytic Activity of Metals and Enzymes for CO2 Reduction to CO

Heine A. Hansen et al.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2013)

Article Chemistry, Physical

Electrocatalytic performance of fuel cell reactions at low catalyst loading and high mass transport

Christopher M. Zalitis et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2013)

Article Materials Science, Multidisciplinary

Emergence of state at Fermi level due to the formation of In-Sn heterodimers on Si(100)-2 x 1

P. Sobotik et al.

PHYSICAL REVIEW B (2013)

Article Chemistry, Multidisciplinary

Electrochemical water splitting by gold: evidence for an oxide decomposition mechanism

Oscar Diaz-Morales et al.

CHEMICAL SCIENCE (2013)

Article Chemistry, Physical

Simulating Linear Sweep Voltammetry from First-Principles: Application to Electrochemical Oxidation of Water on Pt(111) and Pt3Ni(111)

Venkatasubramanian Viswanathan et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2012)

Article Chemistry, Physical

Synthesis and Activities of Rutile IrO2 and RuO2 Nanoparticles for Oxygen Evolution in Acid and Alkaline Solutions

Youngmin Lee et al.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2012)

Article Chemistry, Physical

Activity Descriptors for CO2 Electroreduction to Methane on Transition-Metal Catalysts

Andrew A. Peterson et al.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2012)

Article Chemistry, Multidisciplinary

Biomimetic Oxygen Reduction by Cofacial Porphyrins at a Liquid-Liquid Interface

Pekka Peljo et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2012)

Article Chemistry, Multidisciplinary

Rectangular-Shaped Expanded Phthalocyanines with Two Central Metal Atoms

Osamu Matsushita et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2012)

Article Chemistry, Physical

Structure of the catalytic sites in Fe/N/C-catalysts for O-2-reduction in PEM fuel cells

Ulrike I. Kramm et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2012)

Article Chemistry, Physical

A theoretical evaluation of possible transition metal electro-catalysts for N-2 reduction

Egill Skulason et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2012)

Review Chemistry, Multidisciplinary

Dioxygen Activation in Soluble Methane Monooxygenase

Christine E. Tinberg et al.

ACCOUNTS OF CHEMICAL RESEARCH (2011)

Article Chemistry, Physical

Universality in Oxygen Evolution Electrocatalysis on Oxide Surfaces

Isabela C. Man et al.

CHEMCATCHEM (2011)

Review Chemistry, Multidisciplinary

Tailoring nanoporous materials by atomic layer deposition

Christophe Detavernier et al.

CHEMICAL SOCIETY REVIEWS (2011)

Article Chemistry, Inorganic & Nuclear

Dioxygen and Hydrogen Peroxide Reduction with Hemocyanin Model Complexes

Matthew A. Thorseth et al.

INORGANIC CHEMISTRY (2011)

Article Biochemistry & Molecular Biology

Molybdenum Nitrogenase Catalyzes the Reduction and Coupling of CO to Form Hydrocarbons

Zhi-Yong Yang et al.

JOURNAL OF BIOLOGICAL CHEMISTRY (2011)

Article Chemistry, Multidisciplinary

Tuning the Activity of Pt(111) for Oxygen Electroreduction by Subsurface Alloying

Ifan E. L. Stephens et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2011)

Article Multidisciplinary Sciences

Spectroscopic Observation of Dual Catalytic Sites During Oxidation of CO on a Au/TiO2 Catalyst

Isabel Xiaoye Green et al.

SCIENCE (2011)

Article Multidisciplinary Sciences

Evidence for Interstitial Carbon in Nitrogenase FeMo Cofactor

Thomas Spatzal et al.

SCIENCE (2011)

Review Chemistry, Multidisciplinary

Quantum Chemical Studies of Proton-Coupled Electron Transfer in Metalloenzymes

Per E. M. Siegbahn et al.

CHEMICAL REVIEWS (2010)

Review Chemistry, Multidisciplinary

Atomic Layer Deposition: An Overview

Steven M. George

CHEMICAL REVIEWS (2010)

Article Chemistry, Inorganic & Nuclear

Enzymatic versus Inorganic Oxygen Reduction Catalysts: Comparison of the Energy Levels in a Free-Energy Scheme

Christian H. Kjaergaard et al.

INORGANIC CHEMISTRY (2010)

Review Chemistry, Multidisciplinary

Enzymes as working or inspirational electrocatalysts for fuel cells and electrolysis

James A. Cracknell et al.

CHEMICAL REVIEWS (2008)

Article Chemistry, Physical

Surface Pourbaix diagrams and oxygen reduction activity of Pt, Ag and Ni(111) surfaces studied by DFT

Heine A. Hansen et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2008)

Article Chemistry, Analytical

Electrolysis of water on oxide surfaces

J. Rossmeisl et al.

JOURNAL OF ELECTROANALYTICAL CHEMISTRY (2007)

Review Chemistry, Inorganic & Nuclear

Utilisation of CO2 as a chemical feedstock:: opportunities and challenges

Michele Aresta et al.

DALTON TRANSACTIONS (2007)

Article Chemistry, Physical

Electrolysis of water on (oxidized) metal surfaces

J Rossmeisl et al.

CHEMICAL PHYSICS (2005)

Article Electrochemistry

Trends in the exchange current for hydrogen evolution

JK Norskov et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2005)

Article Chemistry, Physical

Origin of the overpotential for oxygen reduction at a fuel-cell cathode

JK Norskov et al.

JOURNAL OF PHYSICAL CHEMISTRY B (2004)

Article Multidisciplinary Sciences

Catalytic reduction of dinitrogen to ammonia at a single molybdenum center

DV Yandulov et al.

SCIENCE (2003)

Article Chemistry, Multidisciplinary

Reversible dioxygen binding to hemerythrin

M Wirstam et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2003)

Article Chemistry, Physical

Atomic layer deposition of transition metals

BS Lim et al.

NATURE MATERIALS (2003)