4.8 Article

Radical Hydrodehalogenation of Aryl Halides with H2 Catalyzed by a Phenanthroline-Based PNNP Cobalt(I) Complex

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Summary: This perspective article describes the synthesis of a series of Fe and Co complexes coordinated with a meridional PNNP ligand. These complexes exhibit good metal-ligand cooperation and can achieve facile H-H bond cleavage mediated by long-range MLC.

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