期刊
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
卷 648, 期 6, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/zaac.202100159
关键词
SCSC; Transformation; Cadmium complex; Binuclear; Mononuclear
资金
- National Natural Science Foundation of China (NSFC) [21601094, 21401139]
- Tianjin Municipal Education Commission [2018KJ271]
- National College Student Innovation and Entrepreneurship Training Program [202010060001, 202013663039, 201913663023]
A new binuclear complex {[Cd(phen)(2)(H2O)] . (TMA)(2-)}(2) has been synthesized and it can undergo single-crystal-to-single-crystal (SCSC) transformation to a new mononuclear complex [Cd(phen)(3)] . 2(HTMA)(-) . H(2)TMA} by a simple in-situ solvent evaporation method at room temperature without changing the reaction system.
A new binuclear complex {[Cd(phen)(2)(H2O)] . (TMA)(2-)}(2) has been synthesized through the reaction of o-phenanthroline (phen), 3-thiophenemalonic acid (H(2)TMA), and cadmium acetate in a 1 : 2 (v/v) EtOH-H2O mixture at room temperature. This complex can undergo single-crystal-to-single-crystal (SCSC) transformation to a new mononuclear complex [Cd(phen)(3)] . 2(HTMA)(-) . H(2)TMA} by a simple in-situ solvent evaporation method at room temperature without changing the reaction system. In the whole SCSC process, with the solvent water molecules decreasing and the concentration of ligands increasing, the phen ligands replace the coordination water and coordinate with cadmium ions, finally resulting in the crystal structure transformation in the solid state.
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