Synthesis and characterization of arginine-doped heliotrope leaves with high clean-up capacity for crystal violet dye from aqueous media

Novel an arginine-modified Heliotrope leaf (Arg@HL) was used as adsorbent for the crystal violet (CV) dye adsorption in a batch process. The physicochemical and morphological composition of Arg@HL were characterized by field-emission-scanning-electron-microscopy (FE-SEM), Fourier transforms infrared (FT-IR) spectroscopy, thermogravimetric analysis (TGA), differential scanning calorimetry (DSC). The experiments were carried out to investigate the factors that influence the dye uptake by the adsorbent, such as the contact time under agitation, adsorbent amount, initial dye concentration, temperature and pH of dye solution. The optimum conditions of adsorption were found on the batch scale as followed: CV concentration of 20 mg center dot L-1, an amount of 0.75 g center dot L-1 of the adsorbent, 90 min contact time, 6 pH and 25 degrees C temperature for Arg@HL. The results confirmed a second-order model explaining the dye crystal violet's adsorption's kinetics by Arg-Heliotrope leaves. The Langmuir model effectively defines the adsorption isotherms. The results revealed that the Arg@HL has the potential to be used as a low-cost adsorbent for the removal of CV dye from aqueous solutions.

Automated summary

A novel arginine-modified Heliotrope leaf was utilized as an adsorbent for crystal violet dye adsorption. The study identified the optimum conditions for adsorption, confirming the potential of Arg@HL as an effective and low-cost adsorbent for CV dye removal from aqueous solutions.