期刊
SYNTHESIS-STUTTGART
卷 54, 期 5, 页码 1388-1394出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/a-1679-7753
关键词
gemfibrozil; gemfibrozil methyl ester; diaryliodonium salts; Koser's reagent; derivatization
资金
- National Key Research and Development Program of China [2016YFB0401400]
- National Natural Science Foundation of China [22071129, 21871158]
- Department of Education of Guangdong Province [2016KCXTD005]
- Youth Foundation of Wuyi University [2017td01]
Diaryliodonium salts derived from gemfibrozil and gemfibrozil methyl ester were synthesized with good regioselectivity and successfully utilized in various derivatization reactions.
The diaryliodonium salts derived from gemfibrozil and gemfibrozil methyl ester were synthesized from ArI(OH)OTs or bis(4-methoxyphenyl)iodonium diacetate with good regioselectivity. These iodonium salts were successfully used in the derivatization of gemfibrozil or gemfibrozil methyl ester, including fluorination, alkynylation, arylation, etherification, esterification, and iodination reactions.
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