期刊
SYNLETT
卷 33, 期 3, 页码 288-292出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/a-1673-9236
关键词
gold(III) complexes; ligands; pincer complexes; catalysts; multicomponent reactions; chiral complexes
资金
- JSPS KAKENHI [JP20K15268, JP20H04797, JP20H02729]
A series of neutral C,N,N Au(III) complexes were synthesized using different derivatives, allowing changes to both the steric and electronic properties of the complexes for promoting catalytic three-component couplings.
A series of neutral C,N,N Au(III) complexes were synthesized with N -(8-quinolinyl)benzamide derivatives or chiral N -[2-(1,3-oxazolin-2-yl)phenyl]benzamide derivatives. The convenient synthesis method for the amide ligands, together with their operationally simple complexation by direct C-H auration, permitted changes to both the steric and electronic properties of Au(III) complexes for promoting the catalytic three-component couplings of an aldehyde, an amine, and an alkyne.
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