期刊
SYNLETT
卷 33, 期 1, 页码 98-102出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0041-1737140
关键词
palladium catalysis; allylic substitution; [1,3]-rearrangement; imidates; amides
资金
- Research Foundation ITSUU Laboratory
This study introduces a novel strategy for the [1,3]-rearrangement of imidates based on the oxidative addition of a palladium(0) catalyst, enabling the synthesis of structurally distinct allylic amides under mild and base-free conditions.
The rearrangement of allylic imidates is a powerful transformation for the synthesis of allylic amities. Whereas the [3,3]-rearrangement has long been established as the Overman rearrangement, the corresponding [1,3]-rearrangement is rare. Here, we report a novel strategy for the [1,3]-rearrangement of imidates based on the oxidative addition of a palladium(0) catalyst to an allylic imidate. Structurally distinct allylic amides could be synthesized under mild and base-free conditions.
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