Sulfite-triggered surface plasmon-catalyzed reduction of p-nitrothiophenol to p,p′-dimercaptoazobenzene

The conversion of p-aminothiophenol (PATP) or p-nitrothiophenol (PNTP) to p,p'-dimercaptoazobenzene (DMAB) has been used as model reactions to study plasmon-catalyzed reaction on nanoparticles. Herein, we report the conversion of PNTP to DMAB which is triggered by SO32- ions on gold nanoparticles (AuNPs) for the first time. With the addition of SO32-, the Raman peaks at 1139, 1392, 1437 cm(-1) appears, which indicates the formation of DMAB. The experiment results suggested that the synergistic effect of AuNPs and SO32- promoted the conversion of PNTP to DMAB. Besides, the proposed catalysis system is high selectivity to SO32- ions, which provides a new detection route to SO32- ions in the future. More importantly, the possible reaction mechanism has been put forward which is helpful to understand the surface plasmon-assisted catalytic reduction of PNTP on the surface of SERS substrate. (C) 2021 Elsevier B.V. All rights reserved.

Automated summary

The study investigates the mechanism of SO32- ions promoting the conversion of PNTP to DMAB on gold nanoparticles, demonstrating high selectivity and providing a new detection method for SO32- ions in the future.